Optical Studies of Thin Films of Cryocondensed Mixtures of Water and Admixture of Nitrogen and Argon

The interaction of host molecules with water molecules is of primary importance in astrophysical and atmospheric studies. Water-binding interactions continue to attract a broad interest in various fields, especially those related to the formation of assembly structures. Using the physical vapor depo...

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Detalhes bibliográficos
Autores: Sokolov, Dmitriy Y., Yerezhep, Darkhan, Vorobyova, Olga, Shinbayeva, Ainura, Ramos, Miguel A.
Formato: artículo
Fecha de publicación:2022
País:España
Recursos:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/720767
Acesso em linha:http://hdl.handle.net/10486/720767
https://dx.doi.org/10.3390/ma15217441
Access Level:acceso abierto
Palavra-chave:Cryocondensation
glass transition
IR spectrometry
PVD
argon
nitrogen
supercooled thin films
Física
Descrição
Resumo:The interaction of host molecules with water molecules is of primary importance in astrophysical and atmospheric studies. Water-binding interactions continue to attract a broad interest in various fields, especially those related to the formation of assembly structures. Using the physical vapor deposition (PVD) method and a two-beam interferometer with a wavelength of 406 nm, the refractive indices of thin films of a water and nitrogen (argon) mixture were calculated in the range from 15 to 35 K. The results of temperature transformations of the obtained films from a two-beam interferometer, and thermal desorption characteristics from the temperature of condensation to the temperature of evaporation of water (15–180 K), are presented. The relationship between the signal of the interferometer, the refractive index, and the film thickness during glass transition is demonstrated