Selective hydrodeoxygenation of levulinic acid to γ-valerolactone over Ru supported on functionalized carbon nanofibers
In this work, carbon nanofibers (CNFs) have been successfully functionalized by using different approaches and finally used for the preparation of Ru based catalysts. The organometallic approach has been demonstrated to be suitable for CNF functionalization, leading to well-defined Ru NPs (by adding...
| Autores: | , , , , , , , |
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| Formato: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2023 |
| País: | España |
| Recursos: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/354477 |
| Acesso em linha: | http://hdl.handle.net/10261/354477 https://api.elsevier.com/content/abstract/scopus_id/85148689513 |
| Access Level: | acceso abierto |
| Palavra-chave: | Catalytic Conversion Trnasformation Functionalizations Levulinic acid Biomass conversion Graphene Ruthenium Functionalized Solvent Catalyst Carbon nanofibres Platform Vapor-phase hydrogenation Nanoparticles Ru based catalyst Hydrodeoxygenation Chemicals Organosilanes Acid treatments Mineral acid |
| Resumo: | In this work, carbon nanofibers (CNFs) have been successfully functionalized by using different approaches and finally used for the preparation of Ru based catalysts. The organometallic approach has been demonstrated to be suitable for CNF functionalization, leading to well-defined Ru NPs (by adding organosilane, amino or mercapto functionalities, among others) in comparison with mineral acid treatments conventionally used to activate and/or functionalize carbonaceous solids. All catalysts have been tested in levulinic acid hydrodeoxygenation to γ-valerolactone under mild conditions, with the impact of CNF functionalization on the catalysts' performance fully discussed in comparison with unmodified commercial CNFs. |
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