Pursuing efficient systems for glucose transformation to levulinic acid: Homogeneous vs. heterogeneous catalysts and the effect of their co-action
Exploring available catalytic systems to understand their behavior is a must to properly design efficient catalysts aiming to definitively drive biomass from laboratory to industrial scale. Glucose transformation to levulinic acid involves cascade reactions with specific requirements, different acti...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Universidad de Sevilla (US) |
| Repositorio: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/178887 |
| Acceso en línea: | https://hdl.handle.net/11441/178887 https://doi.org/10.1016/j.fuel.2022.123712 |
| Access Level: | acceso abierto |
| Palabra clave: | Tandem homogeneous/heterogeneous catalysis Biomass valorization Glucose conversion Levulinic acid Brønsted/Lewis catalysts |
| Sumario: | Exploring available catalytic systems to understand their behavior is a must to properly design efficient catalysts aiming to definitively drive biomass from laboratory to industrial scale. Glucose transformation to levulinic acid involves cascade reactions with specific requirements, different active sites in each case and secondary reactions hard to avoid which are intrinsically linked to the catalyst’s nature and reaction conditions. In the present work, homogeneous, heterogeneous and heterogeneous/homogeneous catalysts are considered with the unique goal of improving levulinic acid yield while understanding the catalytic behaviour of cost-effective catalysts. The choice of the catalytic systems and the effect of the main reaction parameters on activity and selectivity is studied and discussed. |
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