Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands

The tetranuclear cluster [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] is obtained by reacting the mononuclear platinum complex [NBu4]2[Pt(C6F5)3Cl] with Hg(NO3)2 followed by appropriate work-up. The X-ray study reveals that the compound possesses three donor-acceptor Pt→Hg bonds unsupported by any covalent bridge...

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Autores: Casas, J.M. [0000-0003-0341-7699], Falvello, L.R. [0000-0002-0444-996X], Forniés, J., Gomez, J. [0000-0002-6749-4354], Rueda, A.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2000
País:España
Institución:Universidad de La Rioja (UR)
Repositorio:RIUR. Repositorio Institucional de la Universidad de La Rioja
OAI Identifier:oai:portal.dialnet.es:doc/5bbc6831b750603269e80457
Acceso en línea:https://investigacion.unirioja.es/documentos/5bbc6831b750603269e80457
Access Level:acceso abierto
Palabra clave:Donor-acceptor bond
Luminescence
Platinum-mercury bond
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spelling Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligandsCasas, J.M. [0000-0003-0341-7699]Falvello, L.R. [0000-0002-0444-996X]Forniés, J.Gomez, J. [0000-0002-6749-4354]Rueda, A.Donor-acceptor bondLuminescencePlatinum-mercury bondThe tetranuclear cluster [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] is obtained by reacting the mononuclear platinum complex [NBu4]2[Pt(C6F5)3Cl] with Hg(NO3)2 followed by appropriate work-up. The X-ray study reveals that the compound possesses three donor-acceptor Pt→Hg bonds unsupported by any covalent bridges. The crystallographic parameters are: monoclinic, P21/n with a=11.9770(10), b=26.092(3), c=24.991(2) Å, β=92.900(10)°, Dcalc=2.009 Mg m<sup>-3</sup> for Z=4 and R=0.076 utilizing 13 657 data with Fo<sup>2</sup>≥2σ(Fo<sup>2</sup>). The UV-vis spectrum of the solid sample has been studied revealing that the compound is strongly luminescent. © 2000 Elsevier Science S.A.2000info:eu-repo/semantics/articleSubtype: Articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://investigacion.unirioja.es/documentos/5bbc6831b750603269e80457reponame:RIUR. Repositorio Institucional de la Universidad de La Riojainstname:Universidad de La Rioja (UR)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1016/S0022-328X(99)00604-Xinfo:eu-repo/semantics/altIdentifier/wos/WOS:000084876400053info:eu-repo/semantics/altIdentifier/pissn/0022-328XSynthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands, 2000, vol. 593-594, pág. 421-426info:eu-repo/semantics/openAccessoai:portal.dialnet.es:doc/5bbc6831b750603269e804572026-06-14T12:47:17Z
dc.title.none.fl_str_mv Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands
title Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands
spellingShingle Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands
Casas, J.M. [0000-0003-0341-7699]
Donor-acceptor bond
Luminescence
Platinum-mercury bond
title_short Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands
title_full Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands
title_fullStr Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands
title_full_unstemmed Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands
title_sort Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands
dc.creator.none.fl_str_mv Casas, J.M. [0000-0003-0341-7699]
Falvello, L.R. [0000-0002-0444-996X]
Forniés, J.
Gomez, J. [0000-0002-6749-4354]
Rueda, A.
author Casas, J.M. [0000-0003-0341-7699]
author_facet Casas, J.M. [0000-0003-0341-7699]
Falvello, L.R. [0000-0002-0444-996X]
Forniés, J.
Gomez, J. [0000-0002-6749-4354]
Rueda, A.
author_role author
author2 Falvello, L.R. [0000-0002-0444-996X]
Forniés, J.
Gomez, J. [0000-0002-6749-4354]
Rueda, A.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Donor-acceptor bond
Luminescence
Platinum-mercury bond
topic Donor-acceptor bond
Luminescence
Platinum-mercury bond
description The tetranuclear cluster [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] is obtained by reacting the mononuclear platinum complex [NBu4]2[Pt(C6F5)3Cl] with Hg(NO3)2 followed by appropriate work-up. The X-ray study reveals that the compound possesses three donor-acceptor Pt→Hg bonds unsupported by any covalent bridges. The crystallographic parameters are: monoclinic, P21/n with a=11.9770(10), b=26.092(3), c=24.991(2) Å, β=92.900(10)°, Dcalc=2.009 Mg m<sup>-3</sup> for Z=4 and R=0.076 utilizing 13 657 data with Fo<sup>2</sup>≥2σ(Fo<sup>2</sup>). The UV-vis spectrum of the solid sample has been studied revealing that the compound is strongly luminescent. © 2000 Elsevier Science S.A.
publishDate 2000
dc.date.none.fl_str_mv 2000
dc.type.none.fl_str_mv info:eu-repo/semantics/article
Subtype: Article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://investigacion.unirioja.es/documentos/5bbc6831b750603269e80457
url https://investigacion.unirioja.es/documentos/5bbc6831b750603269e80457
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/S0022-328X(99)00604-X
info:eu-repo/semantics/altIdentifier/wos/WOS:000084876400053
info:eu-repo/semantics/altIdentifier/pissn/0022-328X
Synthesis and structural characterization of the luminescent tetranuclear complex [NBu4]2[(C6F5)6(μ-OH)3Pt3HgCl] with Pt-Hg bonds unsupported by covalent bridging ligands, 2000, vol. 593-594, pág. 421-426
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:RIUR. Repositorio Institucional de la Universidad de La Rioja
instname:Universidad de La Rioja (UR)
instname_str Universidad de La Rioja (UR)
reponame_str RIUR. Repositorio Institucional de la Universidad de La Rioja
collection RIUR. Repositorio Institucional de la Universidad de La Rioja
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.300724

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