A Luminescent Pt3Pb cluster with three Pt(II)®Pb(II) bonds

The reaction between the pentafluorophenylplatinate derivative Pb(ClO4)2 (1.5:1) in dry tetrahydrofuran yields the tetranuclear complex (NBu4)[Pb{Pt(μ-Cl) (C6F5)2}3] (1). The crystal structure of this compound has been analyzed by X-ray diffraction and reveals the presence of three Pt→Pb metal-metal...

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Detalles Bibliográficos
Autores: Ara, I. [0000-0002-5881-9698], Falvello, L.R. [0000-0002-0444-996X], Forniés, J., Gomez-Cordón, J. [0000-0002-6749-4354], Lalinde, E. [0000-0001-7402-1742], Merino, R.I. [0000-0003-0747-405X], Usón, I.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2002
País:España
Institución:Universidad de La Rioja (UR)
Repositorio:RIUR. Repositorio Institucional de la Universidad de La Rioja
OAI Identifier:oai:portal.dialnet.es:doc/5bbc6929b750603269e81655
Acceso en línea:https://investigacion.unirioja.es/documentos/5bbc6929b750603269e81655
Access Level:acceso abierto
Palabra clave:Luminescent properties
Pentafluorophenyl derivatives
Platinum complexes
Pt → Pb bonds
Descripción
Sumario:The reaction between the pentafluorophenylplatinate derivative Pb(ClO4)2 (1.5:1) in dry tetrahydrofuran yields the tetranuclear complex (NBu4)[Pb{Pt(μ-Cl) (C6F5)2}3] (1). The crystal structure of this compound has been analyzed by X-ray diffraction and reveals the presence of three Pt→Pb metal-metal bonds. This complex shows luminescence at low temperature. © 2002 Elsevier Science B.V. All rights reserved.

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