Thermolysis of fibreglass polyester composite and reutilisation of the glass fibre residue to obtain a glass-ceramic material
This study reports the feasibility of reusing glass fibre waste resulting from the thermolysis of polyester fibreglass (PFG) to produce a glass-ceramic material. PFG was treated at 550ºC for 3 h in a 9.6 dm3 thermolytic reactor. This process yielded a solid residue (≈68 wt.%), an oil (≈24 wt.%) and...
| Autores: | , , , , , |
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| Formato: | artículo |
| Fecha de publicación: | 2012 |
| País: | España |
| Recursos: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/62538 |
| Acesso em linha: | http://hdl.handle.net/10261/62538 |
| Access Level: | acceso abierto |
| Palavra-chave: | Thermolysis Glass-ceramic material Polyester fibreglass Glass fibre Vitrification |
| Resumo: | This study reports the feasibility of reusing glass fibre waste resulting from the thermolysis of polyester fibreglass (PFG) to produce a glass-ceramic material. PFG was treated at 550ºC for 3 h in a 9.6 dm3 thermolytic reactor. This process yielded a solid residue (≈68 wt.%), an oil (≈24 wt.%) and a gas (≈8 wt.%). The oil was mainly composed of aromatic (≈84%) and oxygenated compounds (≈16%) and had a fairly high gross calorific value (≈34 MJ kg-1). The major PFG degradation products were styrene, toluene, ethylbenzene, α-methyl styrene, 3-butynyl benzene, benzoic acid and 1,2-benzenedicarboxylic acid anhydride. The gas contained basically CO2 and CO; the hydrocarbon content was below 10 vol%. The higher gross calorific value of the gas was low (26 MJ Nm-3). The solid residue (97 wt% fibreglass, 3 wt% char) was converted into a glass-ceramic material. For this, a mixture consisting of 95 wt% of this solid residue and 5% Na2O was melted at 1450ºC to obtain a glass frit. A powder glass sample (<63 µm) was then sintered and crystallized at 1013ºC, leading to the formation of a glass-ceramic material composed of wollastonite and plagioclase s.s. with possible building applications. |
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