Development of a new glass–ceramic by means of controlled vitrification and crystallisation of inorganic wastes from urban incineration
This paper reports the results of a study of the feasibility of recycling the solid residues from domiciliary waste incineration by producing a glass-ceramic. The major components of the raw material (TIRME F+L), which was from a Spanish domiciliary incinerator, were CaO, SiO2 and Al2O3 but nucleati...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 1999 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/6377 |
| Acceso en línea: | http://hdl.handle.net/10261/6377 |
| Access Level: | acceso abierto |
| Palabra clave: | incinerator waste products microstructure mechanical properties glass ceramics glass vitrification |
| Sumario: | This paper reports the results of a study of the feasibility of recycling the solid residues from domiciliary waste incineration by producing a glass-ceramic. The major components of the raw material (TIRME F+L), which was from a Spanish domiciliary incinerator, were CaO, SiO2 and Al2O3 but nucleating agents, such as TiO2, P2O5, and Fe2O3 were also present in reasonable amounts. It was found that a relatively stable glass with suitable viscosity could be obtained by mixing 65 wt% TIRME F+L with 35 wt% glass cullet. The heat treatment required to crystallise the glass produced from this mixture, designated TIR65, was nucleation at 560°C for 35 min followed by crystal growth at 100°C for 120 min. The resulting glass-ceramic contained a number of crystalline phases, the most stable being clinoenstatite (MgSiO3), or perhaps a pyroxenic phase which incorporates Ca, Mg and Al in its composition, and åkermanite (Ca2MgSi2O7). The microstructure contained both fibre-like and dendritic crystals. The mechanical properties were acceptable for applications such as tiles for the building industry. |
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