Superfluid helium droplet-mediated surface-deposition of neutral and charged silver atomic species.

Experimental and theoretical work has delivered evidence of the helium nanodroplet-mediated synthesis and soft-landing of metal nanoparticles, nanowires, clusters, and single atoms on solid sup- ports. Recent experimental advances have allowed the formation of charged metal clusters into multiply ch...

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Autores: Fernández, Berta, Pi Pericay, Martí, De Lara-Castells, Maria Pilar
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/200464
Acceso en línea:https://hdl.handle.net/2445/200464
Access Level:acceso abierto
Palabra clave:Superfluïdesa
Heli
Nanopartícules
Superfluidity
Helium
Nanoparticles
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spelling Superfluid helium droplet-mediated surface-deposition of neutral and charged silver atomic species.Fernández, BertaPi Pericay, MartíDe Lara-Castells, Maria PilarSuperfluïdesaHeliNanopartículesSuperfluidityHeliumNanoparticlesExperimental and theoretical work has delivered evidence of the helium nanodroplet-mediated synthesis and soft-landing of metal nanoparticles, nanowires, clusters, and single atoms on solid sup- ports. Recent experimental advances have allowed the formation of charged metal clusters into multiply charged helium nanodroplets. The impact of the charge of immersed metal species in helium nanodroplet-mediated surface deposition is proved by considering silver atoms and cations at zero-temperature graphene as the support. By combining high-level ab initio intermolecular inter- action theory with a full quantum description of the superfluid helium nanodroplet motion, evidence is presented that the fundamental mechanism of soft-deposition is preserved in spite of the much stronger interaction of charged species with surfaces, with high-density fluctuations in the helium droplet playing an essential role in braking them. Corroboration is also presented that the soft- landing becomes favored as the helium nanodroplet size increases.Royal Society of Chemistry2023202320232023info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion8 p.application/pdfhttps://hdl.handle.net/2445/200464Articles publicats en revistes (Física Quàntica i Astrofísica)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésReproducció del document publicat a: https://doi.org/10.1039/d3cp01303kPhysical Chemistry Chemical Physics, 2023, vol. 25, p. 16699-16706https://doi.org/10.1039/d3cp01303kcc-by-nc (c) Fernández, Berta et al., 2023http://creativecommons.org/licenses/by-nc/3.0/es/info:eu-repo/semantics/openAccessoai:recercat.cat:2445/2004642026-05-29T05:05:01Z
dc.title.none.fl_str_mv Superfluid helium droplet-mediated surface-deposition of neutral and charged silver atomic species.
title Superfluid helium droplet-mediated surface-deposition of neutral and charged silver atomic species.
spellingShingle Superfluid helium droplet-mediated surface-deposition of neutral and charged silver atomic species.
Fernández, Berta
Superfluïdesa
Heli
Nanopartícules
Superfluidity
Helium
Nanoparticles
title_short Superfluid helium droplet-mediated surface-deposition of neutral and charged silver atomic species.
title_full Superfluid helium droplet-mediated surface-deposition of neutral and charged silver atomic species.
title_fullStr Superfluid helium droplet-mediated surface-deposition of neutral and charged silver atomic species.
title_full_unstemmed Superfluid helium droplet-mediated surface-deposition of neutral and charged silver atomic species.
title_sort Superfluid helium droplet-mediated surface-deposition of neutral and charged silver atomic species.
dc.creator.none.fl_str_mv Fernández, Berta
Pi Pericay, Martí
De Lara-Castells, Maria Pilar
author Fernández, Berta
author_facet Fernández, Berta
Pi Pericay, Martí
De Lara-Castells, Maria Pilar
author_role author
author2 Pi Pericay, Martí
De Lara-Castells, Maria Pilar
author2_role author
author
dc.subject.none.fl_str_mv Superfluïdesa
Heli
Nanopartícules
Superfluidity
Helium
Nanoparticles
topic Superfluïdesa
Heli
Nanopartícules
Superfluidity
Helium
Nanoparticles
description Experimental and theoretical work has delivered evidence of the helium nanodroplet-mediated synthesis and soft-landing of metal nanoparticles, nanowires, clusters, and single atoms on solid sup- ports. Recent experimental advances have allowed the formation of charged metal clusters into multiply charged helium nanodroplets. The impact of the charge of immersed metal species in helium nanodroplet-mediated surface deposition is proved by considering silver atoms and cations at zero-temperature graphene as the support. By combining high-level ab initio intermolecular inter- action theory with a full quantum description of the superfluid helium nanodroplet motion, evidence is presented that the fundamental mechanism of soft-deposition is preserved in spite of the much stronger interaction of charged species with surfaces, with high-density fluctuations in the helium droplet playing an essential role in braking them. Corroboration is also presented that the soft- landing becomes favored as the helium nanodroplet size increases.
publishDate 2023
dc.date.none.fl_str_mv 2023
2023
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/200464
url https://hdl.handle.net/2445/200464
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a: https://doi.org/10.1039/d3cp01303k
Physical Chemistry Chemical Physics, 2023, vol. 25, p. 16699-16706
https://doi.org/10.1039/d3cp01303k
dc.rights.none.fl_str_mv cc-by-nc (c) Fernández, Berta et al., 2023
http://creativecommons.org/licenses/by-nc/3.0/es/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by-nc (c) Fernández, Berta et al., 2023
http://creativecommons.org/licenses/by-nc/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 8 p.
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv Articles publicats en revistes (Física Quàntica i Astrofísica)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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