Easy access to evans’ oxazolidinones. Stereoselective synthesis and antibacterial activity of a new 2-oxazolidinone derivative

An interesting new approach was developed for the synthesis of Evans’ chiral auxiliaries with excellent yields. In turn, another new stereoselective and efficient strategy has also allowed for the preparation of a 2-oxazolidinone derivative in 34% overall yield from the Morita-Baylis-Hillman adduct....

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Detalles Bibliográficos
Autores: Diaz, Gaspar, Freitas, Michelle A. A. de, Ricci-Silva, Maria E., Diaz, Marisa A. N.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2014
País:Brasil
Institución:Universidade Federal de Viçosa (UFV)
Repositorio:LOCUS Repositório Institucional da UFV
Idioma:inglés
OAI Identifier:oai:locus.ufv.br:123456789/12568
Acceso en línea:http://dx.doi.org/10.3390/molecules19067429
http://www.locus.ufv.br/handle/123456789/12568
Access Level:acceso abierto
Palabra clave:Evans’ oxazolidinones
Stereoselective synthesis
Morita-baylis-hillman adduct
Staphylococcus aureus
Mastitis bovina
Descripción
Sumario:An interesting new approach was developed for the synthesis of Evans’ chiral auxiliaries with excellent yields. In turn, another new stereoselective and efficient strategy has also allowed for the preparation of a 2-oxazolidinone derivative in 34% overall yield from the Morita-Baylis-Hillman adduct. The antibacterial activity of this oxazolidinone was tested against Staphylococcus aureus strains isolated from animals with mastitis infections.