Crystalstructure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide
New allylsulfonamide is prepared in a four-step synthetic route: the Morita-Baylis-Hillman adduct prepared from benzaldehyde and acrylonitrile is acetylated using acetic anhydride and DMAP. The acetylated product reacts with DABCO displaced by the addition of 4-methylbenzenesulfonamide. The final pr...
| Autores: | , , , , , |
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| Formato: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2018 |
| País: | Brasil |
| Recursos: | Universidade Federal de Viçosa (UFV) |
| Repositorio: | LOCUS Repositório Institucional da UFV |
| Idioma: | inglés |
| OAI Identifier: | oai:locus.ufv.br:123456789/23785 |
| Acesso em linha: | https://doi.org/10.1134/S0022476618050244 http://www.locus.ufv.br/handle/123456789/23785 |
| Access Level: | acceso abierto |
| Palavra-chave: | Synthesis X-ray crystallographic analysis Allylsulfonamide Morita-Baylis-Hillman adduct |
| Resumo: | New allylsulfonamide is prepared in a four-step synthetic route: the Morita-Baylis-Hillman adduct prepared from benzaldehyde and acrylonitrile is acetylated using acetic anhydride and DMAP. The acetylated product reacts with DABCO displaced by the addition of 4-methylbenzenesulfonamide. The final product is characterized by high-resolution mass spectrometry, infrared, and NMR spectroscopic techniques. The X-ray crystallographic method is used to determine the crystal structure and features of the molecular structure of the compound. |
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