Anthocyanin partition in aqueous two-phase systems based on isopropanol and sodium / ammonium sulfate

Partitioning of anthocyanins contained in the crude extract ofSyzygium cuminifruit was investigated in aqueous two-phase systems (ATPS) made up of isopropa-nol and Na2SO4/(NH4)2SO4.Na2SO4induced ATPS formation more effectivelythan (NH4)2SO4. The increase in temperature enhanced phase separation in t...

ver descrição completa

Detalhes bibliográficos
Autores: Ana Clara Rocha Caldeira, Attilio Converti, Moysés Naves de Moraes, Janaína Teles de Faria
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:Brasil
Recursos:Universidade Federal de Minas Gerais (UFMG)
Repositorio:Repositório Institucional da UFMG
Idioma:inglés
OAI Identifier:oai:repositorio.ufmg.br:1843/59517
Acesso em linha:http://hdl.handle.net/1843/59517
Access Level:acceso abierto
Palavra-chave:Alcohol-salt system
Anthocyanin partition
Liquid-liquid extraction
Naturalpigment
Phase equilibrium
Antocianina
Equilibrio liquido-liquido
Sulfato de sodio
Descrição
Resumo:Partitioning of anthocyanins contained in the crude extract ofSyzygium cuminifruit was investigated in aqueous two-phase systems (ATPS) made up of isopropa-nol and Na2SO4/(NH4)2SO4.Na2SO4induced ATPS formation more effectivelythan (NH4)2SO4. The increase in temperature enhanced phase separation in the(NH4)2SO4ATPS, while the opposite occurred in the Na2SO4ATPS. The higherthe overall mixture concentration or temperature, the higher the values of tie-linelength and slope. In all systems and conditions, anthocyanins preferentially parti-tioned to the top phase. The partition coefficient and theoretical recovery yield inthe top phase varied in the ranges 1.14–1.77 and 53.31–63.87 % in the (NH4)2SO4ATPS, and in the ranges 1.94–21.50 and 65.90–95.55 % in the Na2SO4ATPS.