Theoretical and experimental analysis of the oxidation of CO on Pt catalysts supported on modified TiO2(101)

Abstract The dynamics of the CO adsorption on Pt nanoparticles deposited on TiO2(101) (pure, N-doped and/or reduced) have been investigated using UV-visible diffuse reflectance spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy and density functional theory. The results point...

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Detalles Bibliográficos
Autores: Morgade, Cecilia Ines Nora, Vignatti, Charito Ivana, Avila, Maria Sol, Cabeza, Gabriela Fernanda
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2015
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/78618
Acceso en línea:http://hdl.handle.net/11336/78618
Access Level:acceso abierto
Palabra clave:Co Oxidation
Dft
Drifts
O Vacancies
Pt/N-Tio≪Inf≫2≪/Inf≫(101)
https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
Descripción
Sumario:Abstract The dynamics of the CO adsorption on Pt nanoparticles deposited on TiO2(101) (pure, N-doped and/or reduced) have been investigated using UV-visible diffuse reflectance spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy and density functional theory. The results point to that N-doping and oxygen vacancies in the Pt/N-TiO2 system should favor catalytic reactions in which CO conversion into CO2 takes place mediated by support surface O atoms.