On-surface synthesis of metal-organic frameworks: the critical role of the reaction conditions

Two different metal-organic frameworks with either a honeycomb or Kagome structure were grown on Cu(111) using para-aminophenol molecules and native surface adatoms. Although both frameworks are made up from the same chemical species, they are structurally different emphasizing the critical role bei...

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Bibliographic Details
Authors: Ruiz del Árbol, Nerea, Sánchez Sánchez, Carlos, Martínez, José I., Rodriguez, Luis Miguel, Serrate, David, Verdini, Alberto, Floreano, Luca, Jacobson, Peter, Grill, Leonhard, Martín Gago, José Ángel, López, María F.
Format: article
Status:Published version
Publication Date:2023
Country:Argentina
Institution:Consejo Nacional de Investigaciones Científicas y Técnicas
Repository:CONICET Digital (CONICET)
Language:English
OAI Identifier:oai:ri.conicet.gov.ar:11336/228526
Online Access:http://hdl.handle.net/11336/228526
Access Level:Open access
Keyword:metal-organic framewok
on-surface synthesis
STM
XPS
https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
Description
Summary:Two different metal-organic frameworks with either a honeycomb or Kagome structure were grown on Cu(111) using para-aminophenol molecules and native surface adatoms. Although both frameworks are made up from the same chemical species, they are structurally different emphasizing the critical role being played by the reaction conditions during their growth. This work highlights the importance of the balance between thermodynamics and kinetics in the final structure of surface-supported metal-organic networks.

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