Electrochemical performance comparison of MWCNTs/Ni (OH)₂ composite materials by two preparation routes
Carbon materials are used to improve the nickel hydroxide electrode capacity in rechargeable alkaline batteries. Herein, we present the preparation of multiwall carbon nanotubes/nickel hydroxide composites (MWCNTs/Ni (OH)₂) by two different routes. The first method consists of the direct incorporati...
| Autores: | , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2017 |
| País: | Argentina |
| Institución: | Universidad Nacional de La Plata |
| Repositorio: | SEDICI (UNLP) |
| Idioma: | inglés |
| OAI Identifier: | oai:sedici.unlp.edu.ar:10915/138395 |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/138395 |
| Access Level: | acceso abierto |
| Palabra clave: | Química Física Nickel hydroxide Carbon nanotubes Positive electrode Ni-MH batteries |
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Electrochemical performance comparison of MWCNTs/Ni (OH)₂ composite materials by two preparation routesOrtiz, MarielaCastro, Élida BeatrizReal, Silvia GracielaQuímicaFísicaNickel hydroxideCarbon nanotubesPositive electrodeNi-MH batteriesCarbon materials are used to improve the nickel hydroxide electrode capacity in rechargeable alkaline batteries. Herein, we present the preparation of multiwall carbon nanotubes/nickel hydroxide composites (MWCNTs/Ni (OH)₂) by two different routes. The first method consists of the direct incorporation of MWCNTs in the active material, and the second is based on the hydrothermal synthesis of β-nickel hydroxide, where MWCNTs are added to the precursor solutions. The electrochemical properties of the prepared positive electrodes containing MWCNTs/Ni (OH)₂ composites are studied. Electrochemical results indicate that the active material with MWCNTs incorporated before the hydrothermal synthesis is capable of delivering a higher discharge capacity and exhibits a better reversibility than those composites prepared with MWCNTs after the hydrothermal route.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas2017-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf2339-2347http://sedici.unlp.edu.ar/handle/10915/138395enginfo:eu-repo/semantics/altIdentifier/issn/1432-8488info:eu-repo/semantics/altIdentifier/issn/1433-0768info:eu-repo/semantics/altIdentifier/doi/10.1007/s10008-017-3573-8info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2024-05-08T13:10:31Zoai:sedici.unlp.edu.ar:10915/138395Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292024-05-08 13:10:31.625SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Electrochemical performance comparison of MWCNTs/Ni (OH)₂ composite materials by two preparation routes |
| title |
Electrochemical performance comparison of MWCNTs/Ni (OH)₂ composite materials by two preparation routes |
| spellingShingle |
Electrochemical performance comparison of MWCNTs/Ni (OH)₂ composite materials by two preparation routes Ortiz, Mariela Química Física Nickel hydroxide Carbon nanotubes Positive electrode Ni-MH batteries |
| title_short |
Electrochemical performance comparison of MWCNTs/Ni (OH)₂ composite materials by two preparation routes |
| title_full |
Electrochemical performance comparison of MWCNTs/Ni (OH)₂ composite materials by two preparation routes |
| title_fullStr |
Electrochemical performance comparison of MWCNTs/Ni (OH)₂ composite materials by two preparation routes |
| title_full_unstemmed |
Electrochemical performance comparison of MWCNTs/Ni (OH)₂ composite materials by two preparation routes |
| title_sort |
Electrochemical performance comparison of MWCNTs/Ni (OH)₂ composite materials by two preparation routes |
| dc.creator.none.fl_str_mv |
Ortiz, Mariela Castro, Élida Beatriz Real, Silvia Graciela |
| author |
Ortiz, Mariela |
| author_facet |
Ortiz, Mariela Castro, Élida Beatriz Real, Silvia Graciela |
| author_role |
author |
| author2 |
Castro, Élida Beatriz Real, Silvia Graciela |
| author2_role |
author author |
| dc.subject.none.fl_str_mv |
Química Física Nickel hydroxide Carbon nanotubes Positive electrode Ni-MH batteries |
| topic |
Química Física Nickel hydroxide Carbon nanotubes Positive electrode Ni-MH batteries |
| description |
Carbon materials are used to improve the nickel hydroxide electrode capacity in rechargeable alkaline batteries. Herein, we present the preparation of multiwall carbon nanotubes/nickel hydroxide composites (MWCNTs/Ni (OH)₂) by two different routes. The first method consists of the direct incorporation of MWCNTs in the active material, and the second is based on the hydrothermal synthesis of β-nickel hydroxide, where MWCNTs are added to the precursor solutions. The electrochemical properties of the prepared positive electrodes containing MWCNTs/Ni (OH)₂ composites are studied. Electrochemical results indicate that the active material with MWCNTs incorporated before the hydrothermal synthesis is capable of delivering a higher discharge capacity and exhibits a better reversibility than those composites prepared with MWCNTs after the hydrothermal route. |
| publishDate |
2017 |
| dc.date.none.fl_str_mv |
2017-08 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://sedici.unlp.edu.ar/handle/10915/138395 |
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http://sedici.unlp.edu.ar/handle/10915/138395 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/1432-8488 info:eu-repo/semantics/altIdentifier/issn/1433-0768 info:eu-repo/semantics/altIdentifier/doi/10.1007/s10008-017-3573-8 |
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info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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openAccess |
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http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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application/pdf 2339-2347 |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
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