Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors

A critical revision has been carried out of experimental investigations to quantify the size of the liquid stagnant region in fixed beds with co-current gas-liquid down-flow, and its ability to exchange mass with the dynamic region and with the particle surface. The revision has exposed that a high...

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Detalles Bibliográficos
Autores: Mocciaro, Clarisa, Martinez, Osvaldo Miguel, Barreto, Guillermo Fernando
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2011
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/181006
Acceso en línea:http://hdl.handle.net/11336/181006
Access Level:acceso abierto
Palabra clave:MASS TRANSFER
STAGNANT HOLD-UP
TRICKLE-BED REACTORS
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
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spelling Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactorsMocciaro, ClarisaMartinez, Osvaldo MiguelBarreto, Guillermo FernandoMASS TRANSFERSTAGNANT HOLD-UPTRICKLE-BED REACTORShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A critical revision has been carried out of experimental investigations to quantify the size of the liquid stagnant region in fixed beds with co-current gas-liquid down-flow, and its ability to exchange mass with the dynamic region and with the particle surface. The revision has exposed that a high level of uncertainty arise to estimate, particularly, the mass exchange rate from the available evidence. Therefore, a second purpose is to introduce a geometric model to represent the stagnant region for spherical particles from which, assuming that diffusion is the only mass transport mechanism, it becomes possible to estimate the mass exchange rates with the dynamic region and with the particle surface. Finally, it was discussed why to expect that the geometric model is able to provide a lower bound to mass exchange rate with the dynamic region and a tight lower bound to mass exchange rate with the catalyst surface.Fil: Mocciaro, Clarisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina. Universidad Nacional de La Plata. Facultad de Ingenierí­a. Departamento de Ingeniería Química; ArgentinaFil: Martinez, Osvaldo Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina. Universidad Nacional de La Plata. Facultad de Ingenierí­a. Departamento de Ingeniería Química; ArgentinaFil: Barreto, Guillermo Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina. Universidad Nacional de La Plata. Facultad de Ingenierí­a. Departamento de Ingeniería Química; ArgentinaElsevier Science SA2011-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/181006Mocciaro, Clarisa; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando; Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors; Elsevier Science SA; Chemical Engineering Journal; 173; 3; 10-2011; 813-8271385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1385894711009788info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2011.08.032info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:48:16Zoai:ri.conicet.gov.ar:11336/181006instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:48:16.583CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors
title Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors
spellingShingle Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors
Mocciaro, Clarisa
MASS TRANSFER
STAGNANT HOLD-UP
TRICKLE-BED REACTORS
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
title_short Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors
title_full Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors
title_fullStr Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors
title_full_unstemmed Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors
title_sort Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors
dc.creator.none.fl_str_mv Mocciaro, Clarisa
Martinez, Osvaldo Miguel
Barreto, Guillermo Fernando
author Mocciaro, Clarisa
author_facet Mocciaro, Clarisa
Martinez, Osvaldo Miguel
Barreto, Guillermo Fernando
author_role author
author2 Martinez, Osvaldo Miguel
Barreto, Guillermo Fernando
author2_role author
author
dc.subject.none.fl_str_mv MASS TRANSFER
STAGNANT HOLD-UP
TRICKLE-BED REACTORS
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
topic MASS TRANSFER
STAGNANT HOLD-UP
TRICKLE-BED REACTORS
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
description A critical revision has been carried out of experimental investigations to quantify the size of the liquid stagnant region in fixed beds with co-current gas-liquid down-flow, and its ability to exchange mass with the dynamic region and with the particle surface. The revision has exposed that a high level of uncertainty arise to estimate, particularly, the mass exchange rate from the available evidence. Therefore, a second purpose is to introduce a geometric model to represent the stagnant region for spherical particles from which, assuming that diffusion is the only mass transport mechanism, it becomes possible to estimate the mass exchange rates with the dynamic region and with the particle surface. Finally, it was discussed why to expect that the geometric model is able to provide a lower bound to mass exchange rate with the dynamic region and a tight lower bound to mass exchange rate with the catalyst surface.
publishDate 2011
dc.date.none.fl_str_mv 2011-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/181006
Mocciaro, Clarisa; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando; Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors; Elsevier Science SA; Chemical Engineering Journal; 173; 3; 10-2011; 813-827
1385-8947
CONICET Digital
CONICET
url http://hdl.handle.net/11336/181006
identifier_str_mv Mocciaro, Clarisa; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando; Assessment of mass transfer in the stagnant liquid regions in trickle-bed reactors; Elsevier Science SA; Chemical Engineering Journal; 173; 3; 10-2011; 813-827
1385-8947
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1385894711009788
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2011.08.032
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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