Towards a comprehensive model for liquid flow modulation in trickle bed reactors

The response of an isothermal TBR to a liquid flow modulation ON–OFF strategy is examined through a model aimed at the reactor scale. The reaction is gas-limited and first order with respect to both reactants. Liquid hydrodynamic behavior is considered by means of two different approaches: the Liqui...

ver descrição completa

Detalhes bibliográficos
Autores: Ayude, María Alejandra, Haure, Patricia Monica, Martinez, Osvaldo Miguel, Cassanello, Miryan C.
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2009
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositório:CONICET Digital (CONICET)
Idioma:inglês
OAI Identifier:oai:ri.conicet.gov.ar:11336/30145
Acesso em linha:http://hdl.handle.net/11336/30145
Access Level:Acceso aberto
Palavra-chave:Liquid Flow Modulation
Trickle Bed Reactors
Modeling At the Reactor Scale
Hydrodynamics
https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
Descrição
Resumo:The response of an isothermal TBR to a liquid flow modulation ON–OFF strategy is examined through a model aimed at the reactor scale. The reaction is gas-limited and first order with respect to both reactants. Liquid hydrodynamic behavior is considered by means of two different approaches: the Liquid Draining Approach, based on experimental results and the ideal, Square Wave Approach. Model allows the evaluation of, among other variables, the liquid holdup, the liquid velocity and the liquid reactant conversion time variations at different axial positions within the reactor. An enhancement factor due to periodic operation is defined by computing a temporal average of the liquid reactant conversion during an invariant cycling state, referred to its corresponding steady-state conversion. For all the conditions investigated, attainable enhancements are lower when the actual draining model is assumed.