Liposome-Permeability Templating of Gadolinium Hydroxide Nanostructures

With the growing attention in building novel nanostructures, there is a need for general approaches to controlling the sizes and shapes in precipitation processes. Here, precipitated gadolinium hydroxides (Gd(OH)3) were made in the form of hollow spheres by control of the liposome permeability. Addi...

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Detalles Bibliográficos
Autores: Municoy, Sofia, Bellino, Martin Gonzalo
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2016
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/40576
Acceso en línea:http://hdl.handle.net/11336/40576
Access Level:acceso abierto
Palabra clave:Nanocapsules
Liposomes
Multifunctional Nanostructures
Encapsulation
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
Descripción
Sumario:With the growing attention in building novel nanostructures, there is a need for general approaches to controlling the sizes and shapes in precipitation processes. Here, precipitated gadolinium hydroxides (Gd(OH)3) were made in the form of hollow spheres by control of the liposome permeability. Addition of Gd(NO3)3 to the acidic solution containing the liposomes entrapping OH− creates a self-precipitating template in the precipitation process. The control-formation of these nanostructures takes place through a liposome-membrane phase change. Hybrid nanocapsules are obtained when entrapped hydroxyl ions (OH−) permeates from the liposome and shell material precipitates by forming Gd(OH)3. The morphology of the final product is molded on the original liposome. This synthesis strategy might have implications in significant applications, such as drug delivery systems, and in mineralization, where many processes are also membrane-assisted.