Angle dependence in slow photon photocatalysis using TiO2 inverse opals

The slow photon effect was studied by means of the photocatalytic degradation of stearic acid over TiO2 inverse opals. The comparison of the degradation rates over inverse opals with those obtained over disordered structures at different irradiation angles showed that the irradiation at the blue edg...

Descripción completa

Detalles Bibliográficos
Autores: Curti, Mariano, Zvitco, Gonzalo, Grela, Maria Alejandra, Mendive, Cecilia Beatriz
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2018
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/100707
Acceso en línea:http://hdl.handle.net/11336/100707
Access Level:acceso abierto
Palabra clave:ADVANCED OXIDATION PROCESSES
INVERSE OPALS
PHOTONIC PHOTOCATALYSIS
RCWA METHOD
SLOW PHOTONS
TIO2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
id AR_bf2ebee41476efd20f8a39b440e3bb9c
oai_identifier_str oai:ri.conicet.gov.ar:11336/100707
network_acronym_str AR
network_name_str Argentina
repository_id_str
spelling Angle dependence in slow photon photocatalysis using TiO2 inverse opalsCurti, MarianoZvitco, GonzaloGrela, Maria AlejandraMendive, Cecilia BeatrizADVANCED OXIDATION PROCESSESINVERSE OPALSPHOTONIC PHOTOCATALYSISRCWA METHODSLOW PHOTONSTIO2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The slow photon effect was studied by means of the photocatalytic degradation of stearic acid over TiO2 inverse opals. The comparison of the degradation rates over inverse opals with those obtained over disordered structures at different irradiation angles showed that the irradiation at the blue edge of the stopband leads to the activation of the effect, evidenced by an improvement factor of 1.8 ± 0.6 in the reaction rate for irradiation at 40°. The rigorous coupled-wave analysis (RCWA) method was employed to confirm the source of the enhancement; simulated spectra showed an enhancement in the absorption of the TiO2 matrix that composes the inverse opal at a 40° irradiation angle, owing to an appropriate position of the stopband in relation to the absorption onset of TiO2.Fil: Curti, Mariano. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata; ArgentinaFil: Zvitco, Gonzalo. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; ArgentinaFil: Grela, Maria Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata; ArgentinaFil: Mendive, Cecilia Beatriz. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata; ArgentinaElsevier Science2018-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/100707Curti, Mariano; Zvitco, Gonzalo; Grela, Maria Alejandra; Mendive, Cecilia Beatriz; Angle dependence in slow photon photocatalysis using TiO2 inverse opals; Elsevier Science; Chemical Physics; 502; 3-2018; 33-380301-0104CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S0301010417308583info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemphys.2018.01.007info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:36:24Zoai:ri.conicet.gov.ar:11336/100707instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:36:24.68CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Angle dependence in slow photon photocatalysis using TiO2 inverse opals
title Angle dependence in slow photon photocatalysis using TiO2 inverse opals
spellingShingle Angle dependence in slow photon photocatalysis using TiO2 inverse opals
Curti, Mariano
ADVANCED OXIDATION PROCESSES
INVERSE OPALS
PHOTONIC PHOTOCATALYSIS
RCWA METHOD
SLOW PHOTONS
TIO2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
title_short Angle dependence in slow photon photocatalysis using TiO2 inverse opals
title_full Angle dependence in slow photon photocatalysis using TiO2 inverse opals
title_fullStr Angle dependence in slow photon photocatalysis using TiO2 inverse opals
title_full_unstemmed Angle dependence in slow photon photocatalysis using TiO2 inverse opals
title_sort Angle dependence in slow photon photocatalysis using TiO2 inverse opals
dc.creator.none.fl_str_mv Curti, Mariano
Zvitco, Gonzalo
Grela, Maria Alejandra
Mendive, Cecilia Beatriz
author Curti, Mariano
author_facet Curti, Mariano
Zvitco, Gonzalo
Grela, Maria Alejandra
Mendive, Cecilia Beatriz
author_role author
author2 Zvitco, Gonzalo
Grela, Maria Alejandra
Mendive, Cecilia Beatriz
author2_role author
author
author
dc.subject.none.fl_str_mv ADVANCED OXIDATION PROCESSES
INVERSE OPALS
PHOTONIC PHOTOCATALYSIS
RCWA METHOD
SLOW PHOTONS
TIO2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
topic ADVANCED OXIDATION PROCESSES
INVERSE OPALS
PHOTONIC PHOTOCATALYSIS
RCWA METHOD
SLOW PHOTONS
TIO2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
description The slow photon effect was studied by means of the photocatalytic degradation of stearic acid over TiO2 inverse opals. The comparison of the degradation rates over inverse opals with those obtained over disordered structures at different irradiation angles showed that the irradiation at the blue edge of the stopband leads to the activation of the effect, evidenced by an improvement factor of 1.8 ± 0.6 in the reaction rate for irradiation at 40°. The rigorous coupled-wave analysis (RCWA) method was employed to confirm the source of the enhancement; simulated spectra showed an enhancement in the absorption of the TiO2 matrix that composes the inverse opal at a 40° irradiation angle, owing to an appropriate position of the stopband in relation to the absorption onset of TiO2.
publishDate 2018
dc.date.none.fl_str_mv 2018-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/100707
Curti, Mariano; Zvitco, Gonzalo; Grela, Maria Alejandra; Mendive, Cecilia Beatriz; Angle dependence in slow photon photocatalysis using TiO2 inverse opals; Elsevier Science; Chemical Physics; 502; 3-2018; 33-38
0301-0104
CONICET Digital
CONICET
url http://hdl.handle.net/11336/100707
identifier_str_mv Curti, Mariano; Zvitco, Gonzalo; Grela, Maria Alejandra; Mendive, Cecilia Beatriz; Angle dependence in slow photon photocatalysis using TiO2 inverse opals; Elsevier Science; Chemical Physics; 502; 3-2018; 33-38
0301-0104
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S0301010417308583
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemphys.2018.01.007
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1799194786842804224
score 15,812429

Similares en LA Referencia