Colloidal Photonic Crystal Pigments with Low Angle Dependence

Poly(methyl methacrylate) (PMMA)-based colloidal photonic crystals have an incomplete photonic band gap (PBG) and typically appear iridescent in the visible range. As powders, synthetic PMMA opals are white, but when infiltrated with carbon black nanoparticles, they exhibit a well-defined color that...

Descripción completa

Detalles Bibliográficos
Autores: AGUIRRE, CARLOS I, REGUERA, EDILSO, STEIN, ANDREAS
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2010
País:México
Institución:Instituto Politécnico Nacional
Repositorio:Repositorio Digital del IPN
OAI Identifier:oai:www.repositoriodigital.ipn.mx:123456789/10920
Acceso en línea:http://hdl.handle.net/123456789/431
http://www.repositoriodigital.ipn.mx/handle/123456789/10920
Access Level:acceso abierto
Palabra clave:colloidal photonic crystals
synthetic opals
powder pigments
structural color
Descripción
Sumario:Poly(methyl methacrylate) (PMMA)-based colloidal photonic crystals have an incomplete photonic band gap (PBG) and typically appear iridescent in the visible range. As powders, synthetic PMMA opals are white, but when infiltrated with carbon black nanoparticles, they exhibit a well-defined color that shows little dependence on the viewing angle. The quantity of black pigment determines the lightness of the color by controlling scattering. The combined effects of internal order within each particle and random orientation among the particles in the powder are responsible for this behavior. These pigments were employed as paints, using a mixture of polyvinyl acetate as a binder and deionized water as the solvent, and were applied to wood and paper surfaces for color analysis.