Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism

The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent iso...

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Detalles Bibliográficos
Autores: Guastavino, Javier Fernando, Rossi, Roberto Arturo
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2009
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/21698
Acceso en línea:http://hdl.handle.net/11336/21698
Access Level:acceso abierto
Palabra clave:1,1-Dichlorocyclopropanes
Srn1 Reaction
1,1-Bis(Trimethylstannyl)Cyclopropanes
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
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repository_id_str
spelling Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 MechanismGuastavino, Javier FernandoRossi, Roberto Arturo1,1-DichlorocyclopropanesSrn1 Reaction1,1-Bis(Trimethylstannyl)Cyclopropaneshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent isolated yield (71-90%); 7,7-dichloro-2-oxa-bicyclo[4.1.0]heptane gaVe the 1,1-bis(trimethylstannyl) product in only 40% yield.Fil: Guastavino, Javier Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Rossi, Roberto Arturo. Universidad Nacional de Córdoba; ArgentinaAmerican Chemical Society2009-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/21698Guastavino, Javier Fernando; Rossi, Roberto Arturo; Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism; American Chemical Society; Organometallics; 28; 8; 12-2009; 2646-26490276-7333CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/om801104einfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/om801104einfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T14:18:18Zoai:ri.conicet.gov.ar:11336/21698instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 14:18:18.932CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism
title Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism
spellingShingle Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism
Guastavino, Javier Fernando
1,1-Dichlorocyclopropanes
Srn1 Reaction
1,1-Bis(Trimethylstannyl)Cyclopropanes
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
title_short Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism
title_full Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism
title_fullStr Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism
title_full_unstemmed Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism
title_sort Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism
dc.creator.none.fl_str_mv Guastavino, Javier Fernando
Rossi, Roberto Arturo
author Guastavino, Javier Fernando
author_facet Guastavino, Javier Fernando
Rossi, Roberto Arturo
author_role author
author2 Rossi, Roberto Arturo
author2_role author
dc.subject.none.fl_str_mv 1,1-Dichlorocyclopropanes
Srn1 Reaction
1,1-Bis(Trimethylstannyl)Cyclopropanes
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
topic 1,1-Dichlorocyclopropanes
Srn1 Reaction
1,1-Bis(Trimethylstannyl)Cyclopropanes
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
description The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent isolated yield (71-90%); 7,7-dichloro-2-oxa-bicyclo[4.1.0]heptane gaVe the 1,1-bis(trimethylstannyl) product in only 40% yield.
publishDate 2009
dc.date.none.fl_str_mv 2009-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/21698
Guastavino, Javier Fernando; Rossi, Roberto Arturo; Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism; American Chemical Society; Organometallics; 28; 8; 12-2009; 2646-2649
0276-7333
CONICET Digital
CONICET
url http://hdl.handle.net/11336/21698
identifier_str_mv Guastavino, Javier Fernando; Rossi, Roberto Arturo; Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism; American Chemical Society; Organometallics; 28; 8; 12-2009; 2646-2649
0276-7333
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/om801104e
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/om801104e
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 15.81155

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