Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism
The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent iso...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2009 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/21698 |
| Acceso en línea: | http://hdl.handle.net/11336/21698 |
| Access Level: | acceso abierto |
| Palabra clave: | 1,1-Dichlorocyclopropanes Srn1 Reaction 1,1-Bis(Trimethylstannyl)Cyclopropanes https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| Sumario: | The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent isolated yield (71-90%); 7,7-dichloro-2-oxa-bicyclo[4.1.0]heptane gaVe the 1,1-bis(trimethylstannyl) product in only 40% yield. |
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