Study of the reaction stages and kinetics of the europium oxide carbochlorination

The europium oxide (Eu2O3(s)) chlorination reaction with sucrose carbon was studied by thermogravimetry between room temperature and 1223 K (950 °C). The nonisothermal thermogravimetry showed that the reaction consists of three stages, and their stoichiometries were studied. The product of the first...

Descripción completa

Detalles Bibliográficos
Autores: Pomiro, Federico José, Fouga, Gastón Galo, Gaviría, Juan Pablo, Bohe, Ana Ester
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2014
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/127355
Acceso en línea:http://hdl.handle.net/11336/127355
Access Level:acceso abierto
Palabra clave:Rare Earth
Chlorination
Kinetics
Thermogravimetric
Europium Oxide
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
id AR_b5cbc12f2103160fef3f18cedae8f47e
oai_identifier_str oai:ri.conicet.gov.ar:11336/127355
network_acronym_str AR
network_name_str Argentina
repository_id_str
dc.title.none.fl_str_mv Study of the reaction stages and kinetics of the europium oxide carbochlorination
title Study of the reaction stages and kinetics of the europium oxide carbochlorination
spellingShingle Study of the reaction stages and kinetics of the europium oxide carbochlorination
Pomiro, Federico José
Rare Earth
Chlorination
Kinetics
Thermogravimetric
Europium Oxide
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
title_short Study of the reaction stages and kinetics of the europium oxide carbochlorination
title_full Study of the reaction stages and kinetics of the europium oxide carbochlorination
title_fullStr Study of the reaction stages and kinetics of the europium oxide carbochlorination
title_full_unstemmed Study of the reaction stages and kinetics of the europium oxide carbochlorination
title_sort Study of the reaction stages and kinetics of the europium oxide carbochlorination
dc.creator.none.fl_str_mv Pomiro, Federico José
Fouga, Gastón Galo
Gaviría, Juan Pablo
Bohe, Ana Ester
author Pomiro, Federico José
author_facet Pomiro, Federico José
Fouga, Gastón Galo
Gaviría, Juan Pablo
Bohe, Ana Ester
author_role author
author2 Fouga, Gastón Galo
Gaviría, Juan Pablo
Bohe, Ana Ester
author2_role author
author
author
dc.subject.none.fl_str_mv Rare Earth
Chlorination
Kinetics
Thermogravimetric
Europium Oxide
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
topic Rare Earth
Chlorination
Kinetics
Thermogravimetric
Europium Oxide
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
description The europium oxide (Eu2O3(s)) chlorination reaction with sucrose carbon was studied by thermogravimetry between room temperature and 1223 K (950 °C). The nonisothermal thermogravimetry showed that the reaction consists of three stages, and their stoichiometries were studied. The product of the first stage was europium oxychloride, and it showed independence of the reaction kinetics with the carbon content. Subsequently, in the second stage, the EuOCl(s) was carbochlorinated with formation of EuCl3(l) and its evaporation is observed in the third stage. The analysis by Fourier transform infrared spectroscopy of gaseous species showed that the reaction at second stage occurs with the formation of CO2(g) and CO(g). Both reactants and products were analyzed by X-ray diffraction, scanning electron microscopy and wavelength-dispersive X-ray fluorescence spectroscopy. The influence of carbon content, total flow rate, sample initial mass, chlorine partial pressure, and temperature were evaluated. The second stage kinetics was analyzed, which showed an anomalous behavior caused by generation of chlorine radicals during interaction of Cl2(g) and carbon. It was found that the reaction rate at 933 K (660 °C) was proportional to a potential function of the chlorine partial pressure whose exponent is 0.56. The conversion curves were analyzed with the Avrami-Erofeev model and it was obtained an activation energy of 154 ± 5 kJ mol–1.
publishDate 2014
dc.date.none.fl_str_mv 2014-10-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/127355
Pomiro, Federico José; Fouga, Gastón Galo; Gaviría, Juan Pablo; Bohe, Ana Ester; Study of the reaction stages and kinetics of the europium oxide carbochlorination; Springer; Metallurgical And Materials Transactions B-process Metallurgy And Materials Processing Science; 46; 1; 15-10-2014; 304-315
1073-5615
CONICET Digital
CONICET
url http://hdl.handle.net/11336/127355
identifier_str_mv Pomiro, Federico José; Fouga, Gastón Galo; Gaviría, Juan Pablo; Bohe, Ana Ester; Study of the reaction stages and kinetics of the europium oxide carbochlorination; Springer; Metallurgical And Materials Transactions B-process Metallurgy And Materials Processing Science; 46; 1; 15-10-2014; 304-315
1073-5615
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s11663-014-0196-7
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs11663-014-0196-7
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1799194640839081984
spelling Study of the reaction stages and kinetics of the europium oxide carbochlorinationPomiro, Federico JoséFouga, Gastón GaloGaviría, Juan PabloBohe, Ana EsterRare EarthChlorinationKineticsThermogravimetricEuropium Oxidehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The europium oxide (Eu2O3(s)) chlorination reaction with sucrose carbon was studied by thermogravimetry between room temperature and 1223 K (950 °C). The nonisothermal thermogravimetry showed that the reaction consists of three stages, and their stoichiometries were studied. The product of the first stage was europium oxychloride, and it showed independence of the reaction kinetics with the carbon content. Subsequently, in the second stage, the EuOCl(s) was carbochlorinated with formation of EuCl3(l) and its evaporation is observed in the third stage. The analysis by Fourier transform infrared spectroscopy of gaseous species showed that the reaction at second stage occurs with the formation of CO2(g) and CO(g). Both reactants and products were analyzed by X-ray diffraction, scanning electron microscopy and wavelength-dispersive X-ray fluorescence spectroscopy. The influence of carbon content, total flow rate, sample initial mass, chlorine partial pressure, and temperature were evaluated. The second stage kinetics was analyzed, which showed an anomalous behavior caused by generation of chlorine radicals during interaction of Cl2(g) and carbon. It was found that the reaction rate at 933 K (660 °C) was proportional to a potential function of the chlorine partial pressure whose exponent is 0.56. The conversion curves were analyzed with the Avrami-Erofeev model and it was obtained an activation energy of 154 ± 5 kJ mol–1.Fil: Pomiro, Federico José. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Fouga, Gastón Galo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Gaviría, Juan Pablo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Bohe, Ana Ester. Universidad Nacional del Comahue. Centro Regional Universitario Bariloche; Argentina. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaSpringer2014-10-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/127355Pomiro, Federico José; Fouga, Gastón Galo; Gaviría, Juan Pablo; Bohe, Ana Ester; Study of the reaction stages and kinetics of the europium oxide carbochlorination; Springer; Metallurgical And Materials Transactions B-process Metallurgy And Materials Processing Science; 46; 1; 15-10-2014; 304-3151073-5615CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s11663-014-0196-7info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs11663-014-0196-7info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:33:20Zoai:ri.conicet.gov.ar:11336/127355instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:33:21.097CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
score 15,812429

Similares en LA Referencia