Nucleophilic non-metal assited trifluoromethylation and perfluoroalkylation reactions of organic substrates
Nucleophilic trifluoromethylation and perfluoroalkylation reactions have been the outstanding approach during the last few decades to effect fluoroalkyl group addition or substitution reactions. In most instances, perfluoroalkyl-metal species participate at the beginning of the reactions. In this ac...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2014 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/30212 |
| Acceso en línea: | http://hdl.handle.net/11336/30212 |
| Access Level: | acceso abierto |
| Palabra clave: | Nucleophilic trifluoromethylation Fluoroform Trimethylsilyltrifluoromethane Fluorinated sulfones Fluorinated sulfoxides Fluorinated sulfides https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| Sumario: | Nucleophilic trifluoromethylation and perfluoroalkylation reactions have been the outstanding approach during the last few decades to effect fluoroalkyl group addition or substitution reactions. In most instances, perfluoroalkyl-metal species participate at the beginning of the reactions. In this account, however, the latest nucleophilic non-metal assisted or uncatalyzed trifluoromethylation and perfluoroalkylation reactions of substrates bearing biological relevance will be discussed. |
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