Hyperfine study of Cu3(ZrF 7)2·16H 2 O and its thermal decomposition

By use of the time differential perturbed angular correlations technique, the hyperfine interactions at zirconium sites in Cu2(ZrF7)2·16H2O and its decomposition products were determined between 300 and 700 K. A simple model to give account of the decomposition process is presented in agreement with...

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Detalhes bibliográficos
Autores: Ceolín, Marcelo Raúl, Taylor, Marcela Andrea, Martínez, Jorge Alberto
Formato: artículo
Estado:Versión publicada
Fecha de publicación:1994
País:Argentina
Recursos:Universidad Nacional de La Plata
Repositorio:SEDICI (UNLP)
Idioma:inglés
OAI Identifier:oai:sedici.unlp.edu.ar:10915/138244
Acesso em linha:http://sedici.unlp.edu.ar/handle/10915/138244
Access Level:acceso abierto
Palavra-chave:Química
Ciencias Exactas
hyperfine interactions
decomposition
time differential perturbed angular correlations technique
Descrição
Resumo:By use of the time differential perturbed angular correlations technique, the hyperfine interactions at zirconium sites in Cu2(ZrF7)2·16H2O and its decomposition products were determined between 300 and 700 K. A simple model to give account of the decomposition process is presented in agreement with angular correlation and gravimetric results.