Hyperfine study of Cu3(ZrF 7)2·16H 2 O and its thermal decomposition

By use of the time differential perturbed angular correlations technique, the hyperfine interactions at zirconium sites in Cu2(ZrF7)2·16H2O and its decomposition products were determined between 300 and 700 K. A simple model to give account of the decomposition process is presented in agreement with...

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Bibliographic Details
Authors: Ceolín, Marcelo Raúl, Taylor, Marcela Andrea, Martínez, Jorge Alberto
Format: article
Status:Published version
Publication Date:1994
Country:Argentina
Institution:Universidad Nacional de La Plata
Repository:SEDICI (UNLP)
Language:English
OAI Identifier:oai:sedici.unlp.edu.ar:10915/138244
Online Access:http://sedici.unlp.edu.ar/handle/10915/138244
Access Level:Open access
Keyword:Química
Ciencias Exactas
hyperfine interactions
decomposition
time differential perturbed angular correlations technique
Description
Summary:By use of the time differential perturbed angular correlations technique, the hyperfine interactions at zirconium sites in Cu2(ZrF7)2·16H2O and its decomposition products were determined between 300 and 700 K. A simple model to give account of the decomposition process is presented in agreement with angular correlation and gravimetric results.