Natural designer solvents for greening analytical chemistry
Developing new green solvents is one of the key subjects in Green Chemistry. Ionic liquids and deep eutectic solvents were discovered as an option to replace organic solvents. However, ionic liquids and deep eutectic solvents (DES) have still some limitations to be applied to real chemical industry....
| Autores: | , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2016 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/40050 |
| Acceso en línea: | http://hdl.handle.net/11336/40050 |
| Access Level: | acceso abierto |
| Palabra clave: | Detection Enhancement Green Analytical Chemistry Green Solvents Natural Deep Eutectic Solvents Sample Preparation https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
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Natural designer solvents for greening analytical chemistryEspino, Magdalena BelénFernández, María de Los ÁngelesGomez, Federico Jose VicenteSilva, María FernandaDetection EnhancementGreen Analytical ChemistryGreen SolventsNatural Deep Eutectic SolventsSample Preparationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Developing new green solvents is one of the key subjects in Green Chemistry. Ionic liquids and deep eutectic solvents were discovered as an option to replace organic solvents. However, ionic liquids and deep eutectic solvents (DES) have still some limitations to be applied to real chemical industry. In this sense, a new generation of designer solvents have emerged in the last decade as promising green media. When the compounds that constitute DES are primary metabolites, namely, aminoacids, organic acids, sugars, or choline derivatives, DES are called Natural Deep Eutectic Solvents (NADES). NADES fully represent green chemistry principles. These solvents offer many striking advantages including biodegradability, low toxicity, solute stabilization, sustainability, low costs and simple preparation. Thus, interesting applications in health-related areas can be proposed. This review presents an overview in order to up-to-date knowledge regarding NADES with special emphasis on their analytical applications and further perspectives as truly green solvents.Fil: Espino, Magdalena Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; ArgentinaFil: Fernández, María de Los Ángeles. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; ArgentinaFil: Gomez, Federico Jose Vicente. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Silva, María Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; ArgentinaElsevier2016-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/40050Espino, Magdalena Belén; Fernández, María de Los Ángeles; Gomez, Federico Jose Vicente; Silva, María Fernanda; Natural designer solvents for greening analytical chemistry; Elsevier; Trac-Trends In Analytical Chemistry; 76; 2-2016; 126-1360165-9936CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0165993615300959info:eu-repo/semantics/altIdentifier/doi/10.1016/j.trac.2015.11.006info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:36:42Zoai:ri.conicet.gov.ar:11336/40050instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:36:42.555CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Natural designer solvents for greening analytical chemistry |
| title |
Natural designer solvents for greening analytical chemistry |
| spellingShingle |
Natural designer solvents for greening analytical chemistry Espino, Magdalena Belén Detection Enhancement Green Analytical Chemistry Green Solvents Natural Deep Eutectic Solvents Sample Preparation https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| title_short |
Natural designer solvents for greening analytical chemistry |
| title_full |
Natural designer solvents for greening analytical chemistry |
| title_fullStr |
Natural designer solvents for greening analytical chemistry |
| title_full_unstemmed |
Natural designer solvents for greening analytical chemistry |
| title_sort |
Natural designer solvents for greening analytical chemistry |
| dc.creator.none.fl_str_mv |
Espino, Magdalena Belén Fernández, María de Los Ángeles Gomez, Federico Jose Vicente Silva, María Fernanda |
| author |
Espino, Magdalena Belén |
| author_facet |
Espino, Magdalena Belén Fernández, María de Los Ángeles Gomez, Federico Jose Vicente Silva, María Fernanda |
| author_role |
author |
| author2 |
Fernández, María de Los Ángeles Gomez, Federico Jose Vicente Silva, María Fernanda |
| author2_role |
author author author |
| dc.subject.none.fl_str_mv |
Detection Enhancement Green Analytical Chemistry Green Solvents Natural Deep Eutectic Solvents Sample Preparation https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| topic |
Detection Enhancement Green Analytical Chemistry Green Solvents Natural Deep Eutectic Solvents Sample Preparation https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| description |
Developing new green solvents is one of the key subjects in Green Chemistry. Ionic liquids and deep eutectic solvents were discovered as an option to replace organic solvents. However, ionic liquids and deep eutectic solvents (DES) have still some limitations to be applied to real chemical industry. In this sense, a new generation of designer solvents have emerged in the last decade as promising green media. When the compounds that constitute DES are primary metabolites, namely, aminoacids, organic acids, sugars, or choline derivatives, DES are called Natural Deep Eutectic Solvents (NADES). NADES fully represent green chemistry principles. These solvents offer many striking advantages including biodegradability, low toxicity, solute stabilization, sustainability, low costs and simple preparation. Thus, interesting applications in health-related areas can be proposed. This review presents an overview in order to up-to-date knowledge regarding NADES with special emphasis on their analytical applications and further perspectives as truly green solvents. |
| publishDate |
2016 |
| dc.date.none.fl_str_mv |
2016-02 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/40050 Espino, Magdalena Belén; Fernández, María de Los Ángeles; Gomez, Federico Jose Vicente; Silva, María Fernanda; Natural designer solvents for greening analytical chemistry; Elsevier; Trac-Trends In Analytical Chemistry; 76; 2-2016; 126-136 0165-9936 CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/40050 |
| identifier_str_mv |
Espino, Magdalena Belén; Fernández, María de Los Ángeles; Gomez, Federico Jose Vicente; Silva, María Fernanda; Natural designer solvents for greening analytical chemistry; Elsevier; Trac-Trends In Analytical Chemistry; 76; 2-2016; 126-136 0165-9936 CONICET Digital CONICET |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0165993615300959 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.trac.2015.11.006 |
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info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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openAccess |
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https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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application/pdf application/pdf application/pdf application/pdf application/pdf |
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Elsevier |
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Elsevier |
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reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
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dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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15.812429 |