Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures
Nanowire/nanorod TiO2 structures of approximately 8 nm in diameter and around 1,000 nm long were synthesized by alkaline hydrothermal treatment of two different TiO2 nanopowders. The first precursor was TiO2 obtained by the sol-gel process (SG-TiO2); the second was the well-known commercial TiO2 P-2...
| Autores: | , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2014 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/30829 |
| Acceso en línea: | http://hdl.handle.net/11336/30829 |
| Access Level: | acceso abierto |
| Palabra clave: | 1d Tio2 Nanostructures Hydrothermal Treatment Photocatalytic Activity https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
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Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructuresCabrera, JulietaAlarcón Cavero, Hugo ArturoLópez, AlcidesCandal, Roberto JorgeAcosta, DwightRodríguez, Juan1d Tio2 NanostructuresHydrothermal TreatmentPhotocatalytic Activityhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Nanowire/nanorod TiO2 structures of approximately 8 nm in diameter and around 1,000 nm long were synthesized by alkaline hydrothermal treatment of two different TiO2 nanopowders. The first precursor was TiO2 obtained by the sol-gel process (SG-TiO2); the second was the well-known commercial TiO2 P-25 (P25-TiO2). Anatase-like 1D TiO2 nanostructures were obtained in both cases. The one-dimensional (1D) nanostructures synthesized from SG-TiO2 powders turned into rod-like nanostructures after annealing at 400 °C for 2 h. Conversely, the nanostructures synthesized from P25-TiO2 preserved the tubular structure after annealing, displaying a higher Brunauer–Emmett–Teller surface area than the first system (279 and 97 m2/g, respectively). Despite the higher surface area shown by the 1D nanostructures, in both cases the photocatalytic activity was lower than for the P25-TiO2 powder. However, the rod-like nanostructures obtained from SG-TiO2 displayed slightly higher efficiency than the sol-gel prepared powders. The lower photocatalytic activity of the nanostructures with respect to P-25 can be associated with the lower crystallinity of 1D TiO2 in both materials.Fil: Cabrera, Julieta. Universidad Nacional de Ingeniería; PerúFil: Alarcón Cavero, Hugo Arturo. Universidad Nacional de Ingeniería; Perú. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: López, Alcides. Universidad Nacional de Ingeniería; Perú. Instituto Peruano de Energía Nuclear; PerúFil: Candal, Roberto Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Acosta, Dwight. Universidad Nacional Autónoma de México; MéxicoFil: Rodríguez, Juan. Universidad Nacional de Ingeniería; PerúIWA Publishing2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/30829Cabrera, Julieta; Alarcón Cavero, Hugo Arturo; López, Alcides; Candal, Roberto Jorge; Acosta, Dwight; et al.; Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures; IWA Publishing; Water Science And Technology; 70; 6; 1-2014; 972-9790273-1223CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.2166/wst.2014.312info:eu-repo/semantics/altIdentifier/url/http://wst.iwaponline.com/content/70/6/972info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:36:13Zoai:ri.conicet.gov.ar:11336/30829instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:36:14.266CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures |
| title |
Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures |
| spellingShingle |
Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures Cabrera, Julieta 1d Tio2 Nanostructures Hydrothermal Treatment Photocatalytic Activity https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| title_short |
Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures |
| title_full |
Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures |
| title_fullStr |
Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures |
| title_full_unstemmed |
Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures |
| title_sort |
Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures |
| dc.creator.none.fl_str_mv |
Cabrera, Julieta Alarcón Cavero, Hugo Arturo López, Alcides Candal, Roberto Jorge Acosta, Dwight Rodríguez, Juan |
| author |
Cabrera, Julieta |
| author_facet |
Cabrera, Julieta Alarcón Cavero, Hugo Arturo López, Alcides Candal, Roberto Jorge Acosta, Dwight Rodríguez, Juan |
| author_role |
author |
| author2 |
Alarcón Cavero, Hugo Arturo López, Alcides Candal, Roberto Jorge Acosta, Dwight Rodríguez, Juan |
| author2_role |
author author author author author |
| dc.subject.none.fl_str_mv |
1d Tio2 Nanostructures Hydrothermal Treatment Photocatalytic Activity https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| topic |
1d Tio2 Nanostructures Hydrothermal Treatment Photocatalytic Activity https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| description |
Nanowire/nanorod TiO2 structures of approximately 8 nm in diameter and around 1,000 nm long were synthesized by alkaline hydrothermal treatment of two different TiO2 nanopowders. The first precursor was TiO2 obtained by the sol-gel process (SG-TiO2); the second was the well-known commercial TiO2 P-25 (P25-TiO2). Anatase-like 1D TiO2 nanostructures were obtained in both cases. The one-dimensional (1D) nanostructures synthesized from SG-TiO2 powders turned into rod-like nanostructures after annealing at 400 °C for 2 h. Conversely, the nanostructures synthesized from P25-TiO2 preserved the tubular structure after annealing, displaying a higher Brunauer–Emmett–Teller surface area than the first system (279 and 97 m2/g, respectively). Despite the higher surface area shown by the 1D nanostructures, in both cases the photocatalytic activity was lower than for the P25-TiO2 powder. However, the rod-like nanostructures obtained from SG-TiO2 displayed slightly higher efficiency than the sol-gel prepared powders. The lower photocatalytic activity of the nanostructures with respect to P-25 can be associated with the lower crystallinity of 1D TiO2 in both materials. |
| publishDate |
2014 |
| dc.date.none.fl_str_mv |
2014-01 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/30829 Cabrera, Julieta; Alarcón Cavero, Hugo Arturo; López, Alcides; Candal, Roberto Jorge; Acosta, Dwight; et al.; Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures; IWA Publishing; Water Science And Technology; 70; 6; 1-2014; 972-979 0273-1223 CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/30829 |
| identifier_str_mv |
Cabrera, Julieta; Alarcón Cavero, Hugo Arturo; López, Alcides; Candal, Roberto Jorge; Acosta, Dwight; et al.; Synthesis, characterization and photocatalytic activity of 1D TiO2 nanostructures; IWA Publishing; Water Science And Technology; 70; 6; 1-2014; 972-979 0273-1223 CONICET Digital CONICET |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.2166/wst.2014.312 info:eu-repo/semantics/altIdentifier/url/http://wst.iwaponline.com/content/70/6/972 |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
| eu_rights_str_mv |
openAccess |
| rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
| dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
| dc.publisher.none.fl_str_mv |
IWA Publishing |
| publisher.none.fl_str_mv |
IWA Publishing |
| dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
| reponame_str |
CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
| repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1799194779366457344 |
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15.81155 |