Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents

Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant c...

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Detalles Bibliográficos
Autores: Ojeda, Gonzalo Adrian, Vallejos, Margarita, Sgroppo, Sonia Cecilia, Sánchez Moreno, Concepción, de Ancos, Begoña
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/224878
Acceso en línea:http://hdl.handle.net/11336/224878
Access Level:acceso abierto
Palabra clave:BIOACTIVE
DFT
EUTECTIC SOLVENT
MANGIFERIN
MANGO
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
id AR_7b4e926fb83dccade27ea12eeca7aa9d
oai_identifier_str oai:ri.conicet.gov.ar:11336/224878
network_acronym_str AR
network_name_str Argentina
repository_id_str
dc.title.none.fl_str_mv Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
title Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
spellingShingle Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
Ojeda, Gonzalo Adrian
BIOACTIVE
DFT
EUTECTIC SOLVENT
MANGIFERIN
MANGO
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
title_short Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
title_full Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
title_fullStr Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
title_full_unstemmed Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
title_sort Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
dc.creator.none.fl_str_mv Ojeda, Gonzalo Adrian
Vallejos, Margarita
Sgroppo, Sonia Cecilia
Sánchez Moreno, Concepción
de Ancos, Begoña
author Ojeda, Gonzalo Adrian
author_facet Ojeda, Gonzalo Adrian
Vallejos, Margarita
Sgroppo, Sonia Cecilia
Sánchez Moreno, Concepción
de Ancos, Begoña
author_role author
author2 Vallejos, Margarita
Sgroppo, Sonia Cecilia
Sánchez Moreno, Concepción
de Ancos, Begoña
author2_role author
author
author
author
dc.subject.none.fl_str_mv BIOACTIVE
DFT
EUTECTIC SOLVENT
MANGIFERIN
MANGO
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
topic BIOACTIVE
DFT
EUTECTIC SOLVENT
MANGIFERIN
MANGO
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
description Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant capacity and HPLC-DAD profile. A theoretical study was performed using density functional theory and the QTAIM approach. β-alanine and choline chloride based DESs were effective to extract PC from peel and seed. Some DES increased PC extraction up to three times for peel (23.05 ± 1.22 mg/g DW) and up to five time for seeds (60.01 ± 1.40 mg/g DW). The PC profile varied with the solvent (DES vs EtOH/MeOH), procedure (US vs agitation) and material (peel or seed). Mangiferin extraction from peels was significantly increased with β-alanine based DES (676.08 ± 20.34 μg/gDW). The strength of H-bonds had a determining effect on the viscosity of DESs. The solute-solvent solvation energy was suitable to estimate the strength of H-bond interactions between DES and target compounds. This study demonstrates the remarkable capacity of DESs to extract PC from mango by-products and provides insights into the factors controlling extraction properties.
publishDate 2023
dc.date.none.fl_str_mv 2023-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/224878
Ojeda, Gonzalo Adrian; Vallejos, Margarita; Sgroppo, Sonia Cecilia; Sánchez Moreno, Concepción; de Ancos, Begoña; Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents; Elsevier; Heliyon; 9; 6; 6-2023; 1-14
2405-8440
CONICET Digital
CONICET
url http://hdl.handle.net/11336/224878
identifier_str_mv Ojeda, Gonzalo Adrian; Vallejos, Margarita; Sgroppo, Sonia Cecilia; Sánchez Moreno, Concepción; de Ancos, Begoña; Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents; Elsevier; Heliyon; 9; 6; 6-2023; 1-14
2405-8440
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2405844023041191
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.heliyon.2023.e16912
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1799194669625638912
spelling Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solventsOjeda, Gonzalo AdrianVallejos, MargaritaSgroppo, Sonia CeciliaSánchez Moreno, Concepciónde Ancos, BegoñaBIOACTIVEDFTEUTECTIC SOLVENTMANGIFERINMANGOhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant capacity and HPLC-DAD profile. A theoretical study was performed using density functional theory and the QTAIM approach. β-alanine and choline chloride based DESs were effective to extract PC from peel and seed. Some DES increased PC extraction up to three times for peel (23.05 ± 1.22 mg/g DW) and up to five time for seeds (60.01 ± 1.40 mg/g DW). The PC profile varied with the solvent (DES vs EtOH/MeOH), procedure (US vs agitation) and material (peel or seed). Mangiferin extraction from peels was significantly increased with β-alanine based DES (676.08 ± 20.34 μg/gDW). The strength of H-bonds had a determining effect on the viscosity of DESs. The solute-solvent solvation energy was suitable to estimate the strength of H-bond interactions between DES and target compounds. This study demonstrates the remarkable capacity of DESs to extract PC from mango by-products and provides insights into the factors controlling extraction properties.Fil: Ojeda, Gonzalo Adrian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; ArgentinaFil: Vallejos, Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; ArgentinaFil: Sgroppo, Sonia Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; ArgentinaFil: Sánchez Moreno, Concepción. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnologia de Alimentos y Nutrición; EspañaFil: de Ancos, Begoña. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnologia de Alimentos y Nutrición; EspañaElsevier2023-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/224878Ojeda, Gonzalo Adrian; Vallejos, Margarita; Sgroppo, Sonia Cecilia; Sánchez Moreno, Concepción; de Ancos, Begoña; Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents; Elsevier; Heliyon; 9; 6; 6-2023; 1-142405-8440CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2405844023041191info:eu-repo/semantics/altIdentifier/doi/10.1016/j.heliyon.2023.e16912info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:33:56Zoai:ri.conicet.gov.ar:11336/224878instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:33:57.066CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
score 15.811543

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