Efficient Routes to Racemic and Enantiomerically Pure (S)-BINOL Diesters
A systematic study for esterification procedures to the synthesis of BINOL diesters is described. Reaction conditions with TFAA and 85% H3PO4 were selected as the best procedure to prepare enantiomerically pure (S)-BINOL diesters VIII to XI with almost quantitative yields and very low reaction times...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2013 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/101840 |
| Acceso en línea: | http://hdl.handle.net/11336/101840 |
| Access Level: | acceso abierto |
| Palabra clave: | DIOLS ESTERIFICATION PHASE-TRANSFER CATALYSIS DIESTERS BINOL C2 SYMETRY https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| Sumario: | A systematic study for esterification procedures to the synthesis of BINOL diesters is described. Reaction conditions with TFAA and 85% H3PO4 were selected as the best procedure to prepare enantiomerically pure (S)-BINOL diesters VIII to XI with almost quantitative yields and very low reaction times. |
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