Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)

We report the synthesis, FTIR, Raman and NMR spectroscopic features of bis(triphenylphosphine)iminium and tetrabutylammonium thiosaccharinates, PNP(tsac) and NBu₄(tsac) (tsac: thiosaccharinate anion, PNP: bis(triphenylphosphine)iminium). The molecular structure of the former compound was determined...

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Detalles Bibliográficos
Autores: Dennehy, Mariana, Quinzani, Oscar V., Mandolesi, Sandra D., Güida, Jorge Alberto, Echeverría, Gustavo Alberto, Piro, Oscar Enrique
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2007
País:Argentina
Institución:Universidad Nacional de La Plata
Repositorio:SEDICI (UNLP)
Idioma:inglés
OAI Identifier:oai:sedici.unlp.edu.ar:10915/146350
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/146350
Access Level:acceso abierto
Palabra clave:Física
Química
Thiosaccharin
Bis(triphenylphosphine)iminium
IR spectroscopy
NMR spectroscopy
X-Ray structure determination
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spelling Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)Dennehy, MarianaQuinzani, Oscar V.Mandolesi, Sandra D.Güida, Jorge AlbertoEcheverría, Gustavo AlbertoPiro, Oscar EnriqueFísicaQuímicaThiosaccharinBis(triphenylphosphine)iminiumIR spectroscopyNMR spectroscopyX-Ray structure determinationWe report the synthesis, FTIR, Raman and NMR spectroscopic features of bis(triphenylphosphine)iminium and tetrabutylammonium thiosaccharinates, PNP(tsac) and NBu₄(tsac) (tsac: thiosaccharinate anion, PNP: bis(triphenylphosphine)iminium). The molecular structure of the former compound was determined by X-ray diffraction methods. The salt crystallizes in the monoclinic P2₁/n space group with a = 9.6481(9), b = 29.258(3), c = 13.177(2) Å, β = 97.53(1)°, and Z = 4 molecules per unit cell. Slight but significant changes in the bonding structure of the thiosaccharinate anion as compared with those reported for the neutral molecule are observed.Centro de Química InorgánicaInstituto de Física La Plata2007-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf669-675http://sedici.unlp.edu.ar/handle/10915/146350enginfo:eu-repo/semantics/altIdentifier/issn/0026-9247info:eu-repo/semantics/altIdentifier/issn/1434-4475info:eu-repo/semantics/altIdentifier/issn/0343-7329info:eu-repo/semantics/altIdentifier/doi/10.1007/s00706-007-0648-8info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2024-05-08T13:10:47Zoai:sedici.unlp.edu.ar:10915/146350Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292024-05-08 13:10:47.715SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)
title Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)
spellingShingle Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)
Dennehy, Mariana
Física
Química
Thiosaccharin
Bis(triphenylphosphine)iminium
IR spectroscopy
NMR spectroscopy
X-Ray structure determination
title_short Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)
title_full Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)
title_fullStr Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)
title_full_unstemmed Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)
title_sort Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)
dc.creator.none.fl_str_mv Dennehy, Mariana
Quinzani, Oscar V.
Mandolesi, Sandra D.
Güida, Jorge Alberto
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
author Dennehy, Mariana
author_facet Dennehy, Mariana
Quinzani, Oscar V.
Mandolesi, Sandra D.
Güida, Jorge Alberto
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
author_role author
author2 Quinzani, Oscar V.
Mandolesi, Sandra D.
Güida, Jorge Alberto
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Física
Química
Thiosaccharin
Bis(triphenylphosphine)iminium
IR spectroscopy
NMR spectroscopy
X-Ray structure determination
topic Física
Química
Thiosaccharin
Bis(triphenylphosphine)iminium
IR spectroscopy
NMR spectroscopy
X-Ray structure determination
description We report the synthesis, FTIR, Raman and NMR spectroscopic features of bis(triphenylphosphine)iminium and tetrabutylammonium thiosaccharinates, PNP(tsac) and NBu₄(tsac) (tsac: thiosaccharinate anion, PNP: bis(triphenylphosphine)iminium). The molecular structure of the former compound was determined by X-ray diffraction methods. The salt crystallizes in the monoclinic P2₁/n space group with a = 9.6481(9), b = 29.258(3), c = 13.177(2) Å, β = 97.53(1)°, and Z = 4 molecules per unit cell. Slight but significant changes in the bonding structure of the thiosaccharinate anion as compared with those reported for the neutral molecule are observed.
publishDate 2007
dc.date.none.fl_str_mv 2007-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/146350
url http://sedici.unlp.edu.ar/handle/10915/146350
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0026-9247
info:eu-repo/semantics/altIdentifier/issn/1434-4475
info:eu-repo/semantics/altIdentifier/issn/0343-7329
info:eu-repo/semantics/altIdentifier/doi/10.1007/s00706-007-0648-8
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
669-675
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 15,81155

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