Solvation dynamics following electron photodetachment from l- in aqueous clusters
New insights into equilibrium and dynamical aspects of electron photodetachment reactions in small water clusters were given. It focuses on assessing the effects of thermal and polarization fluctuations provided by three cluster environments with different extents of spatial confinement, on the micr...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2002 |
| País: | Argentina |
| Institución: | Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales |
| Repositorio: | Biblioteca Digital (UBA-FCEN) |
| Idioma: | inglés |
| OAI Identifier: | paperaa:paper_00219606_v117_n5_p2238_Elola |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00219606_v117_n5_p2238_Elola |
| Access Level: | acceso abierto |
| Palabra clave: | Algorithms Chemical relaxation Diffusion Electronic properties Ground state Mathematical models Molecular structure Photochemical reactions Quantum theory Solutions Diffuse density profile Electron photodetachment Electronic excitation Equilibrium solvation structures Solvation dynamics Surface states Molecular dynamics |
| Sumario: | New insights into equilibrium and dynamical aspects of electron photodetachment reactions in small water clusters were given. It focuses on assessing the effects of thermal and polarization fluctuations provided by three cluster environments with different extents of spatial confinement, on the microscopic mechanisms that drive the reaction. These fluctuations, in turn, determine the characteristics of the electron localization and the subsequent detachment following photoexcitation of the probe. |
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