Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling

Films cast from multiphase polymer particles have the potential to combine the properties of their components synergistically. The properties of the film depend on the hybrid polymer architecture and the film morphology. However, how the polymer microstructure and particle morphology are transformed...

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Autores: Goikoetxea, Monika, Reyes, Yuri, de Las Heras Alarcón, Carolina, Minari, Roque Javier, Beristain, Itxaso, Paulis, María, Barandiaran, María J., Keddie, Joseph L., Asua, José M.
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2012
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/10962
Acesso em linha:http://hdl.handle.net/11336/10962
Access Level:acceso abierto
Palavra-chave:Alkyd/Acrylic Nanocomposites
Particles And Film Morphology
Mathematical Simulation
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
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spelling Transformation of waterborne hybrid polymer particles into films: Morphology development and modellingGoikoetxea, MonikaReyes, Yuride Las Heras Alarcón, CarolinaMinari, Roque JavierBeristain, ItxasoPaulis, MaríaBarandiaran, María J.Keddie, Joseph L.Asua, José M.Alkyd/Acrylic NanocompositesParticles And Film MorphologyMathematical Simulationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Films cast from multiphase polymer particles have the potential to combine the properties of their components synergistically. The properties of the film depend on the hybrid polymer architecture and the film morphology. However, how the polymer microstructure and particle morphology are transformed during film formation to determine the film morphology is not well understood. Here, using waterborne alkyd-acrylic nanocomposite particles in a case study, it was found that phase migration leading to the formation of aggregates occurred during film formation. A coarse-grained Monte Carlo model was developed to account for the effects of polymer microstructure and particle morphology on the morphology of the film. The model was validated by comparing its predictions with the observed effects, and then used to explore combinations of polymer microstructure and particle morphology not attainable with the system used as a case study. Significantly, the compatibility of the phases was found to have a greater influence than the morphology of the particles in determining the film structure.Fil: Goikoetxea, Monika. Universidad del Pais Vasco; EspañaFil: Reyes, Yuri. Universidad del Pais Vasco; EspañaFil: de Las Heras Alarcón, Carolina. University of Surrey; Reino UnidoFil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Universidad del Pais Vasco; EspañaFil: Beristain, Itxaso. Universidad del Pais Vasco; EspañaFil: Paulis, María. Universidad del Pais Vasco; EspañaFil: Barandiaran, María J.. Universidad del Pais Vasco; EspañaFil: Keddie, Joseph L.. University of Surrey; Reino UnidoFil: Asua, José M.. Universidad del Pais Vasco; EspañaElsevier2012-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10962Goikoetxea, Monika; Reyes, Yuri; de Las Heras Alarcón, Carolina; Minari, Roque Javier; Beristain, Itxaso; et al.; Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling; Elsevier; Polymer; 53; 5; 1-2012; 1098-11080032-3861enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2012.01.021info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0032386112000468info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:43:22Zoai:ri.conicet.gov.ar:11336/10962instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:43:23.074CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling
title Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling
spellingShingle Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling
Goikoetxea, Monika
Alkyd/Acrylic Nanocomposites
Particles And Film Morphology
Mathematical Simulation
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
title_short Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling
title_full Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling
title_fullStr Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling
title_full_unstemmed Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling
title_sort Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling
dc.creator.none.fl_str_mv Goikoetxea, Monika
Reyes, Yuri
de Las Heras Alarcón, Carolina
Minari, Roque Javier
Beristain, Itxaso
Paulis, María
Barandiaran, María J.
Keddie, Joseph L.
Asua, José M.
author Goikoetxea, Monika
author_facet Goikoetxea, Monika
Reyes, Yuri
de Las Heras Alarcón, Carolina
Minari, Roque Javier
Beristain, Itxaso
Paulis, María
Barandiaran, María J.
Keddie, Joseph L.
Asua, José M.
author_role author
author2 Reyes, Yuri
de Las Heras Alarcón, Carolina
Minari, Roque Javier
Beristain, Itxaso
Paulis, María
Barandiaran, María J.
Keddie, Joseph L.
Asua, José M.
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Alkyd/Acrylic Nanocomposites
Particles And Film Morphology
Mathematical Simulation
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
topic Alkyd/Acrylic Nanocomposites
Particles And Film Morphology
Mathematical Simulation
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
description Films cast from multiphase polymer particles have the potential to combine the properties of their components synergistically. The properties of the film depend on the hybrid polymer architecture and the film morphology. However, how the polymer microstructure and particle morphology are transformed during film formation to determine the film morphology is not well understood. Here, using waterborne alkyd-acrylic nanocomposite particles in a case study, it was found that phase migration leading to the formation of aggregates occurred during film formation. A coarse-grained Monte Carlo model was developed to account for the effects of polymer microstructure and particle morphology on the morphology of the film. The model was validated by comparing its predictions with the observed effects, and then used to explore combinations of polymer microstructure and particle morphology not attainable with the system used as a case study. Significantly, the compatibility of the phases was found to have a greater influence than the morphology of the particles in determining the film structure.
publishDate 2012
dc.date.none.fl_str_mv 2012-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/10962
Goikoetxea, Monika; Reyes, Yuri; de Las Heras Alarcón, Carolina; Minari, Roque Javier; Beristain, Itxaso; et al.; Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling; Elsevier; Polymer; 53; 5; 1-2012; 1098-1108
0032-3861
url http://hdl.handle.net/11336/10962
identifier_str_mv Goikoetxea, Monika; Reyes, Yuri; de Las Heras Alarcón, Carolina; Minari, Roque Javier; Beristain, Itxaso; et al.; Transformation of waterborne hybrid polymer particles into films: Morphology development and modelling; Elsevier; Polymer; 53; 5; 1-2012; 1098-1108
0032-3861
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2012.01.021
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0032386112000468
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 15,811543

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