Post-polymerization of waterborne alkyd/acrylics. Effect on polymer architecture and particle morphology
The limiting conversion commonly attained in the synthesis of waterborne alkyd/acrylic hybrid latexes hinders their industrialization. In the first part of this work, the mechanisms causing the limiting conversion are studied and post-polymerization conditions to efficiently remove the residual mono...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2009 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/17110 |
| Acceso en línea: | http://hdl.handle.net/11336/17110 |
| Access Level: | acceso abierto |
| Palabra clave: | Miniemulsion Polymerization Alkyds/Acrylics Post-Polymerization https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
| Sumario: | The limiting conversion commonly attained in the synthesis of waterborne alkyd/acrylic hybrid latexes hinders their industrialization. In the first part of this work, the mechanisms causing the limiting conversion are studied and post-polymerization conditions to efficiently remove the residual monomer determined. Both the polymer architecture and the particle morphology were modified. Therefore, in the second part the mechanisms involved in this modification were investigated in an attempt to transform a potential threat for the material properties in an opportunity to expand the range of properties achievable. |
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