STRUCTURAL REFINEMENT OF [Y1-xCax]SrBaCu2.80(PO4)0.20Oy

[Y1-xCax]SrBaCu2.80(PO4)0.20Oy samples with 0.10 ≤ x ≤ 0.40 were syntherized using the solid state reaction technique. X-ray diffraction patterns show that all the compounds crystallized into a 123 tetragonal structure. The analysis of the structure with Rietveld refinement wer...

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Detalles Bibliográficos
Autores: González González, Juan Carlos, Landinez Tellez, D. A., Albino Aguiar, J., Bustamante Dominguez, Angel Guillermo
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2000
País:Perú
Institución:Universidad Nacional Mayor de San Marcos
Repositorio:Revistas - Universidad Nacional Mayor de San Marcos
Idioma:español
OAI Identifier:oai:revistasinvestigacion.unmsm.edu.pe:article/8606
Acceso en línea:https://revistasinvestigacion.unmsm.edu.pe/index.php/fisica/article/view/8606
Access Level:acceso abierto
Palabra clave:synthesis
Rietveld refinement
superconductivity
phosphate
síntesis
refinamiento Rietveld
superconductividad
fosfato
Descripción
Sumario:[Y1-xCax]SrBaCu2.80(PO4)0.20Oy samples with 0.10 ≤ x ≤ 0.40 were syntherized using the solid state reaction technique. X-ray diffraction patterns show that all the compounds crystallized into a 123 tetragonal structure. The analysis of the structure with Rietveld refinement were made using a model that contains one Cu(2) in four coordination and not in five coordination as in the other 123 tetragonal structures. This fact allows that Tc increase with Ca concentration. All samples are superconductors as reported in a previous paper.