Enhancement of charge carrier transport by doping PVK-based photoconductive polymers with LiNbO₃ nanocrystals

The photoconductive properties of a hybrid material based on poly(N-vinylcarbazole) (PVK) doped with nanoparticles of lithium niobate (LiNbO₃) have been studied. The experiments were carried out using modulated photocurrent and non-steady-state photo-emf techniques at 633 nm wavelength. The photocon...

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Bibliographic Details
Author: SVETLANA MANSUROVA SERGUEYEVNA
Format: article
Status:Versión aceptada para publicación
Publication Date:2009
Country:México
Institution:Instituto Nacional de Astrofísica, Óptica y Electrónica
Repository:Repositorio Institucional del INAOE
Language:English
OAI Identifier:oai:inaoe.repositorioinstitucional.mx:1009/1214
Online Access:http://inaoe.repositorioinstitucional.mx/jspui/handle/1009/1214
Access Level:Open access
Keyword:info:eu-repo/classification/cti/1
info:eu-repo/classification/cti/22
info:eu-repo/classification/cti/2209
info:eu-repo/classification/cti/220919
Description
Summary:The photoconductive properties of a hybrid material based on poly(N-vinylcarbazole) (PVK) doped with nanoparticles of lithium niobate (LiNbO₃) have been studied. The experiments were carried out using modulated photocurrent and non-steady-state photo-emf techniques at 633 nm wavelength. The photoconductivity of the composite increases remarkably with the nanoparticle content. This growth is related to larger drift lengths of the photoholes at higher nanoparticle concentrations. The reason for this enhancement is an increase in the effective photohole lifetime due to trapping of electrons on the nanoparticles and creation of recombination barriers at the polymer/nanoparticle interface.