Synthesis of zeolitic materials from volcanic ash in presence and absence of cetyltrimethylammonium bromide

Zeolitic materials as Na-phillipsite, Na-K-phillipsite-like zeolites and the mixtures of zeolites (phillipsite+analcime and phillipsite+chabazite+analcime) were synthesized from volcanic ash, either in presence and absence of cetiltrimetilamonium bromide (CTAB). The ash sample used in the laboratory...

Descripción completa

Detalles Bibliográficos
Autores: Sanhueza Núñez, Vilma Mayerling, Bennun Torres, Leonardo Daniel
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2015
País:México
Institución:UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO
Repositorio:Revista Internacional de Contaminación Ambiental
Idioma:español
OAI Identifier:oai:ojs.pkp.sfu.ca:article/45223
Acceso en línea:https://www.revistascca.unam.mx/rica/index.php/rica/article/view/45223
Access Level:acceso abierto
Palabra clave:zeolites
phillipsite
chabazite
analcime
ash
synthesis
zeolitas
phillipsita
chabazita
analcima
ceniza
síntesis
Descripción
Sumario:Zeolitic materials as Na-phillipsite, Na-K-phillipsite-like zeolites and the mixtures of zeolites (phillipsite+analcime and phillipsite+chabazite+analcime) were synthesized from volcanic ash, either in presence and absence of cetiltrimetilamonium bromide (CTAB). The ash sample used in the laboratory experiments contains 75.36 % SiO2 and 14.11 % Al2O3, abundances. The reaction time as well as the influence of CTAB were studied in the zeolitic materials crystallization. The experiments were carried out under hydrothermal conditions, autogenic pressure and temperature of 150 ºC, as well as reaction time from 8 to 116 h. Products from this hydrotermal treatment were identified by X-ray diffraction (XRD) and characterized by scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS). Of the zeolitic materials obtained the Na-K-phillipsite-like zeolite was found to be the most effective for the retention of cations Pb2+, Zn2+, and Ba2+.