Adsorption and separation of light alkane hydrocarbons by porous hexacyanocobaltates (III)

The adsorption and separation of light n-alkane hydrocarbons (propane, butane, pentane, hexane and heptane) by zinc and cadmium hexacyanocobaltates (III) were studied from inverse gas chromatographic data. These two solids are representative of the porous frameworks found for transition metals hexac...

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Autores: AUTIE CASTRO, G., AUTIE, M., REGUERA, E., SANTAMARIA GONZALEZ, J., MORENO TOST, R., RODRIGUEZ CASTELLON, E., JIMENEZ LOPEZ, A.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2009
País:México
Institución:Instituto Politécnico Nacional
Repositorio:Repositorio Digital del IPN
OAI Identifier:oai:www.repositoriodigital.ipn.mx:123456789/10990
Acceso en línea:http://hdl.handle.net/123456789/503
http://www.repositoriodigital.ipn.mx/handle/123456789/10990
Access Level:acceso abierto
Palabra clave:porous solids
n-alkane separation
inverse gas chromatography
n-alkane adsorption
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spelling Adsorption and separation of light alkane hydrocarbons by porous hexacyanocobaltates (III)AUTIE CASTRO, G.AUTIE, M.REGUERA, E.SANTAMARIA GONZALEZ, J.MORENO TOST, R.RODRIGUEZ CASTELLON, E.JIMENEZ LOPEZ, A.porous solidsn-alkane separationinverse gas chromatographyn-alkane adsorptionThe adsorption and separation of light n-alkane hydrocarbons (propane, butane, pentane, hexane and heptane) by zinc and cadmium hexacyanocobaltates (III) were studied from inverse gas chromatographic data. These two solids are representative of the porous frameworks found for transition metals hexacyanometallates. For cadmium, the porous framework is related to the presence of systematic vacancies for the building block, [Co(CN)6], while for Zn it is a consequence of a tetrahedral coordination for the Zn atom. These linear light hydrocarbons (paraffins) are effectively separated by these two porous frameworks. The involved differential adsorption heats and the related separation coefficients were estimated from the recorded chromatographic data. No significant differences for the separation ability of light n-alkane hydrocarbons by the evaluatedmaterials were observed. Copyright c 2009 JohnWiley & Sons, Ltd.InterScience2012-03-27T00:40:12Z2012-03-27T00:40:12Z2009-05-272013-01-16T11:39:27Z2013-01-16T11:39:27Z2013-01-16info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleSurf. Interface Anal. 2009, 41, 730–734http://hdl.handle.net/123456789/503http://www.repositoriodigital.ipn.mx/handle/123456789/10990reponame:Repositorio Digital del IPNinstname:Instituto Politécnico Nacionalinstacron:IPNeninfo:eu-repo/semantics/openAccessoai:www.repositoriodigital.ipn.mx:123456789/109902026-02-18T16:40:50Z
dc.title.none.fl_str_mv Adsorption and separation of light alkane hydrocarbons by porous hexacyanocobaltates (III)
title Adsorption and separation of light alkane hydrocarbons by porous hexacyanocobaltates (III)
spellingShingle Adsorption and separation of light alkane hydrocarbons by porous hexacyanocobaltates (III)
AUTIE CASTRO, G.
porous solids
n-alkane separation
inverse gas chromatography
n-alkane adsorption
title_short Adsorption and separation of light alkane hydrocarbons by porous hexacyanocobaltates (III)
title_full Adsorption and separation of light alkane hydrocarbons by porous hexacyanocobaltates (III)
title_fullStr Adsorption and separation of light alkane hydrocarbons by porous hexacyanocobaltates (III)
title_full_unstemmed Adsorption and separation of light alkane hydrocarbons by porous hexacyanocobaltates (III)
title_sort Adsorption and separation of light alkane hydrocarbons by porous hexacyanocobaltates (III)
dc.creator.none.fl_str_mv AUTIE CASTRO, G.
AUTIE, M.
REGUERA, E.
SANTAMARIA GONZALEZ, J.
MORENO TOST, R.
RODRIGUEZ CASTELLON, E.
JIMENEZ LOPEZ, A.
author AUTIE CASTRO, G.
author_facet AUTIE CASTRO, G.
AUTIE, M.
REGUERA, E.
SANTAMARIA GONZALEZ, J.
MORENO TOST, R.
RODRIGUEZ CASTELLON, E.
JIMENEZ LOPEZ, A.
author_role author
author2 AUTIE, M.
REGUERA, E.
SANTAMARIA GONZALEZ, J.
MORENO TOST, R.
RODRIGUEZ CASTELLON, E.
JIMENEZ LOPEZ, A.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv porous solids
n-alkane separation
inverse gas chromatography
n-alkane adsorption
topic porous solids
n-alkane separation
inverse gas chromatography
n-alkane adsorption
description The adsorption and separation of light n-alkane hydrocarbons (propane, butane, pentane, hexane and heptane) by zinc and cadmium hexacyanocobaltates (III) were studied from inverse gas chromatographic data. These two solids are representative of the porous frameworks found for transition metals hexacyanometallates. For cadmium, the porous framework is related to the presence of systematic vacancies for the building block, [Co(CN)6], while for Zn it is a consequence of a tetrahedral coordination for the Zn atom. These linear light hydrocarbons (paraffins) are effectively separated by these two porous frameworks. The involved differential adsorption heats and the related separation coefficients were estimated from the recorded chromatographic data. No significant differences for the separation ability of light n-alkane hydrocarbons by the evaluatedmaterials were observed. Copyright c 2009 JohnWiley & Sons, Ltd.
publishDate 2009
dc.date.none.fl_str_mv 2009-05-27
2012-03-27T00:40:12Z
2012-03-27T00:40:12Z
2013-01-16T11:39:27Z
2013-01-16T11:39:27Z
2013-01-16
dc.type.none.fl_str_mv info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv Surf. Interface Anal. 2009, 41, 730–734
http://hdl.handle.net/123456789/503
http://www.repositoriodigital.ipn.mx/handle/123456789/10990
identifier_str_mv Surf. Interface Anal. 2009, 41, 730–734
url http://hdl.handle.net/123456789/503
http://www.repositoriodigital.ipn.mx/handle/123456789/10990
dc.language.none.fl_str_mv en
language_invalid_str_mv en
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv InterScience
publisher.none.fl_str_mv InterScience
dc.source.none.fl_str_mv reponame:Repositorio Digital del IPN
instname:Instituto Politécnico Nacional
instacron:IPN
instname_str Instituto Politécnico Nacional
instacron_str IPN
institution IPN
reponame_str Repositorio Digital del IPN
collection Repositorio Digital del IPN
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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