Stability constants of manganese(II) alkylenediaminetetraacetates

Ethylenediaminetetraacetic acids are abundant chelating agents in the aquatic environment due to their numerous industrial applications. One of the main environmental effects of these substances is the mobilization of metals, and for this reason it is important to evaluate the corresponding affinity...

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Detalhes bibliográficos
Autor: Sierra Trejo, Pamela Viridiana
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2013
País:México
Recursos:UNIVERSIDAD AUTÓNOMA DEL ESTADO DE HIDALGO
Repositorio:PÄDI Boletín Científico de Ciencias Básicas e Ingeniería del ICBI
Idioma:español
OAI Identifier:oai:repository.uaeh.edu.mx:article/495
Acesso em linha:https://repository.uaeh.edu.mx/revistas/index.php/icbi/article/view/495
Access Level:acceso abierto
Palavra-chave:Chelating agents, manganese, affinity constants
Agentes quelantes, manganeso, constantes de afinidad
Descrição
Resumo:Ethylenediaminetetraacetic acids are abundant chelating agents in the aquatic environment due to their numerous industrial applications. One of the main environmental effects of these substances is the mobilization of metals, and for this reason it is important to evaluate the corresponding affinity constants. In this work, affinity constants of Mn (II) and two common chelating agents (EDTA and HPDTA) were measured by affinity potentiometry, in media with different ionic strengths. It was found that HPDTA forms stable complexes with Mn2+ in a wide range of pH values, and that the stability of these complexes is lower than that of the Mn-EDTA complexes.