Melt-processing of SBS/polyaniline-based blends
Morphological analysis and electrical conductivity of composites obtained by melt-processing of blends of a polyaniline complex (PANICX) with styrene-butadiene-styrene (SBS) are reported. Blends with PANICX contents ranging from 1 to 50 wt% were first prepared using a two-piece batch mixer, followed...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2013 |
| País: | México |
| Institución: | Centro de Investigación Científica de Yucatán |
| Repositorio: | Redalyc-CICY |
| OAI Identifier: | oai:redalyc.org:49626817012 |
| Acceso en línea: | https://www.redalyc.org/articulo.oa?id=49626817012 |
| Access Level: | acceso abierto |
| Palabra clave: | Ingeniería Extrusion Polymer blends Microstructure Polymer processing Conducting polymers |
| Sumario: | Morphological analysis and electrical conductivity of composites obtained by melt-processing of blends of a polyaniline complex (PANICX) with styrene-butadiene-styrene (SBS) are reported. Blends with PANICX contents ranging from 1 to 50 wt% were first prepared using a two-piece batch mixer, followed by ram-extrusion to obtain cord-like extrudates. The microstructure was analyzed by SEM, and conductivity was evaluated with a Keithley electrometer. The blends’ rheological behavior was also studied. Evidence of formation of well-defined elongated structures was found in most of the extrudates. The extrudates’ conductivity was considerably low. Inhomogeneityrelated problems were observed such as erratic behavior of pressure, “melt-fracture” during the extrusion, and extrudates with irregular microstructure and very low conductivity. This occurred because same size batches were used regardless of blends’ composition. As a result, the shearing occurring during compounding was not enough to disperse PANICX effectively within the SBS matrix. |
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