Band gap energy in Zn-rich Zn1¡xCdxTe thin films grown by r.f. sputtering

Ternary Zn1¡xCdxTe semiconducting thin films were grown on 7059 Corning glass substrates at room temperature by co-sputtering froma ZnTe-Cd target. The visible Cd-area onto ZnTe target was varied to cover 0% - 4% of the total area. The optical and structural properties ofthe films were analysed as a...

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Detalles Bibliográficos
Autores: M. Becerril, H. Silva López, O. Zelaya Angel
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2004
País:México
Institución:Centro de Investigación y de Estudios Avanzados del IPN
Repositorio:Redalyc-CINVESTAV
OAI Identifier:oai:redalyc.org:57050606
Acceso en línea:https://www.redalyc.org/articulo.oa?id=57050606
Access Level:acceso abierto
Palabra clave:Física, Astronomía y Matemáticas
II
ZnCdTe
thin films
VI semiconductors
radio frequency sputtering
Descripción
Sumario:Ternary Zn1¡xCdxTe semiconducting thin films were grown on 7059 Corning glass substrates at room temperature by co-sputtering froma ZnTe-Cd target. The visible Cd-area onto ZnTe target was varied to cover 0% - 4% of the total area. The optical and structural properties ofthe films were analysed as a function of the Cd concentration (x) on the layers. The sharp diffraction lines indicate mainly the ZnTe in cubicphase. When the cadmium was incorporated into the ZnTe lattice, the band gap energy (Eg) decreased from 2.2748 eV (x=0) to 2.2226 eV(x= 0.081). We found a linear relationship between Eg and (x) in the interval of (x) studied, that predicts a value of the bowing parameter bin the Eg(x) = Ego +ax+bx2 relationship, which coincides with the value of b calculated by making the same study for Cd-rich CdZnTe.This result becomes interesting given the large number of values reported for b and a for Eg(x) of this ternary material.