Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from water

There has been growing interest in making adsorbents more cost-effective and feasible in low resource areas by using material that is cheap or would usually be considered waste. In the present study, a high-capacity regenerable adsorbent is synthesized by the treatment of waste tire rubber (WTR) wit...

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Autores: Ricardo Saenz-Arana, Cesar Hernandez, Thomas Guinto, Md Ariful Ahsan, Dwayne Bragg, Huiyao Wang, Bonifacio Alvarado-Tenorio, Juan C. Noveron, Tariqul Islam
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2018
País:México
Institución:Universidad Autónoma de Ciudad Juárez
Repositorio:Repositorio Institucional de la Universidad Autónoma de Ciudad Juárez
OAI Identifier:oai:uacj.mx:oai:cathi.uacj.mx:20.500.11961ir-4696
Acceso en línea:https://doi.org/10.1016/j.jece.2018.04.058
Access Level:acceso abierto
Palabra clave:Adsorption
Methyl orange
Methylene blue
Tetracycline
Waste tire
rubber Sulfonation
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spelling Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from waterRicardo Saenz-AranaCesar HernandezThomas GuintoMd Ariful AhsanDwayne BraggHuiyao WangBonifacio Alvarado-TenorioJuan C. NoveronTariqul IslamAdsorptionMethyl orangeMethylene blueTetracyclineWaste tirerubber Sulfonationinfo:eu-repo/classification/cti/7There has been growing interest in making adsorbents more cost-effective and feasible in low resource areas by using material that is cheap or would usually be considered waste. In the present study, a high-capacity regenerable adsorbent is synthesized by the treatment of waste tire rubber (WTR) with concentrated sulfuric acid. The sulfuric acid reflux carbonized as well as functionalized the WTR with the sulfonic acid group. The as-prepared sulfonated carbonaceous WTR was used for the removal of organic dyes and antibiotic viz. methylene blue (MB), methyl orange (MO) and Tetracycline (TC) from water. The maximum adsorption capacity was found to be about 833, 588, and 303 mg/g towards MB, MO, and TC, respectively. The adsorption of MB, MO, and TC from the tap water matrix was also performed and shown to maintain similar adsorption capacities as the deionized water. In addition, a packed glass column was prepared to demonstrate the continuous adsorption of MB and TC from the tap water matrix. The regeneration of the column was achieved by using mixture of aqueous and organic solvents with dissolved NaOH and it was demonstrated that the adsorbent not only recovered but also increased its adsorption capacity after every time it was regenerated.Ricardo Saenz-AranaCesar HernandezThomas GuintoAriful AhsanDwayne BraggHuiyao WangBonifacio Alvarado-TenorioJuan C. Noveron2018info:eu-repo/semantics/articleArtículoinfo:eu-repo/semantics/publishedVersionhttps://doi.org/10.1016/j.jece.2018.04.058reponame:Repositorio Institucional de la Universidad Autónoma de Ciudad Juárezinstname:Universidad Autónoma de Ciudad Juárezinstacron:UACJEnglishinfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc/4.0oai:uacj.mx:oai:cathi.uacj.mx:20.500.11961ir-46962025-11-26T19:47:10Z
dc.title.none.fl_str_mv Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from water
title Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from water
spellingShingle Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from water
Ricardo Saenz-Arana
Adsorption
Methyl orange
Methylene blue
Tetracycline
Waste tire
rubber Sulfonation
info:eu-repo/classification/cti/7
title_short Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from water
title_full Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from water
title_fullStr Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from water
title_full_unstemmed Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from water
title_sort Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from water
dc.creator.none.fl_str_mv Ricardo Saenz-Arana
Cesar Hernandez
Thomas Guinto
Md Ariful Ahsan
Dwayne Bragg
Huiyao Wang
Bonifacio Alvarado-Tenorio
Juan C. Noveron
Tariqul Islam
author Ricardo Saenz-Arana
author_facet Ricardo Saenz-Arana
Cesar Hernandez
Thomas Guinto
Md Ariful Ahsan
Dwayne Bragg
Huiyao Wang
Bonifacio Alvarado-Tenorio
Juan C. Noveron
Tariqul Islam
author_role author
author2 Cesar Hernandez
Thomas Guinto
Md Ariful Ahsan
Dwayne Bragg
Huiyao Wang
Bonifacio Alvarado-Tenorio
Juan C. Noveron
Tariqul Islam
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ricardo Saenz-Arana
Cesar Hernandez
Thomas Guinto
Ariful Ahsan
Dwayne Bragg
Huiyao Wang
Bonifacio Alvarado-Tenorio
Juan C. Noveron
dc.subject.none.fl_str_mv Adsorption
Methyl orange
Methylene blue
Tetracycline
Waste tire
rubber Sulfonation
info:eu-repo/classification/cti/7
topic Adsorption
Methyl orange
Methylene blue
Tetracycline
Waste tire
rubber Sulfonation
info:eu-repo/classification/cti/7
description There has been growing interest in making adsorbents more cost-effective and feasible in low resource areas by using material that is cheap or would usually be considered waste. In the present study, a high-capacity regenerable adsorbent is synthesized by the treatment of waste tire rubber (WTR) with concentrated sulfuric acid. The sulfuric acid reflux carbonized as well as functionalized the WTR with the sulfonic acid group. The as-prepared sulfonated carbonaceous WTR was used for the removal of organic dyes and antibiotic viz. methylene blue (MB), methyl orange (MO) and Tetracycline (TC) from water. The maximum adsorption capacity was found to be about 833, 588, and 303 mg/g towards MB, MO, and TC, respectively. The adsorption of MB, MO, and TC from the tap water matrix was also performed and shown to maintain similar adsorption capacities as the deionized water. In addition, a packed glass column was prepared to demonstrate the continuous adsorption of MB and TC from the tap water matrix. The regeneration of the column was achieved by using mixture of aqueous and organic solvents with dissolved NaOH and it was demonstrated that the adsorbent not only recovered but also increased its adsorption capacity after every time it was regenerated.
publishDate 2018
dc.date.none.fl_str_mv 2018
dc.type.none.fl_str_mv info:eu-repo/semantics/article
Artículo
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://doi.org/10.1016/j.jece.2018.04.058
url https://doi.org/10.1016/j.jece.2018.04.058
dc.language.none.fl_str_mv English
language_invalid_str_mv English
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc/4.0
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc/4.0
dc.source.none.fl_str_mv reponame:Repositorio Institucional de la Universidad Autónoma de Ciudad Juárez
instname:Universidad Autónoma de Ciudad Juárez
instacron:UACJ
instname_str Universidad Autónoma de Ciudad Juárez
instacron_str UACJ
institution UACJ
reponame_str Repositorio Institucional de la Universidad Autónoma de Ciudad Juárez
collection Repositorio Institucional de la Universidad Autónoma de Ciudad Juárez
repository.name.fl_str_mv
repository.mail.fl_str_mv
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