Low temperature redetermination of the Glycine sodium nitrate structure by using X-ray single crystal diffraction technique

The redetermined structure of glycine sodium nitrate, C2H5N2NaO5, at 150°K is reported. The compound has an overall polymeric structure whilst the glycine molecule is found in the zwitterionic form. GSN crystals were characterized by XRD powder diffraction, FTIR, UV-VIS, and DTA-TGA techniques. XRD...

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Detalles Bibliográficos
Autores: JAVIER HERNANDEZ PAREDES, Hilda Esparza Ponce, MARIO ENRIQUE ALVAREZ RAMOS, JOSE ALBERTO DUARTE MOLLER
Tipo de recurso: artículo
Estado:Versión enviada para evaluación y publicación
Fecha de publicación:2008
País:México
Institución:Centro de Investigación en Materiales Avanzados
Repositorio:Fuente de Objetos Científicos Open Access del CIMAV
Idioma:inglés
OAI Identifier:oai:cimav.repositorioinstitucional.mx:1004/970
Acceso en línea:http://cimav.repositorioinstitucional.mx/jspui/handle/1004/970
Access Level:acceso abierto
Palabra clave:info:eu-repo/classification/XRD/Polymers
info:eu-repo/classification/UV-Vis/FTIR
info:eu-repo/classification/cti/1
info:eu-repo/classification/cti/22
info:eu-repo/classification/cti/2299
info:eu-repo/classification/cti/229999
Descripción
Sumario:The redetermined structure of glycine sodium nitrate, C2H5N2NaO5, at 150°K is reported. The compound has an overall polymeric structure whilst the glycine molecule is found in the zwitterionic form. GSN crystals were characterized by XRD powder diffraction, FTIR, UV-VIS, and DTA-TGA techniques. XRD revealed that GSN have a monoclinic structure and space group Cc. Infrared spectra confirmed that the chemical elements and functional groups are present in the crystals and also collaborated the zwiterionic form of molecule. Ultraviolet-Visible spectra showed a wide optical transparent window in the range of 340-1100 nm, which is a desirable characteristic for nonlinear optics applications. DTA-TGA analysis determined that the material is stable up to 198°C.