Micro- and macromechanical properties of a composite with a ternary PLA-PCL-TPS matrix reinforced with short fique fibers

Biocomposites were prepared from a ternary matrix of polylactic acid (PLA), polycaprolactone (PCL), and thermoplastic starch (TPS) and reinforced with native fique fibers from southwestern Colombia. The influence of surface modification by alkalization of fique fibers on the interfacial properties o...

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Detalles Bibliográficos
Autores: José Herminsul Mina Hernández, Alex Valadez González, MARIO FERNANDO MUÑOZ VELEZ
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2020
País:México
Institución:Centro de Investigación Científica de Yucatán
Repositorio:Repositorio Institucional CICY
Idioma:inglés
OAI Identifier:oai:cicy.repositorioinstitucional.mx:1003/1831
Acceso en línea:http://cicy.repositorioinstitucional.mx/jspui/handle/1003/1831
Access Level:acceso abierto
Palabra clave:info:eu-repo/classification/Autores/BIODEGRADABLE POLYMERS
info:eu-repo/classification/Autores/FIBER/MATRIX BOND
info:eu-repo/classification/Autores/FIBERS
info:eu-repo/classification/Autores/TERNARY BLENDS
info:eu-repo/classification/cti/7
info:eu-repo/classification/cti/33
info:eu-repo/classification/cti/3312
info:eu-repo/classification/cti/331208
Descripción
Sumario:Biocomposites were prepared from a ternary matrix of polylactic acid (PLA), polycaprolactone (PCL), and thermoplastic starch (TPS) and reinforced with native fique fibers from southwestern Colombia. The influence of surface modification by alkalization of fique fibers on the interfacial properties of the biocomposite was studied using pull-out tests. Additionally, the effect of short fique fibers in three proportions (10%, 20%, and 30% (w/w)) on the tensile mechanical properties of the composite was evaluated. The experimental results indicated that the interfacial shear strength (IFSS) of the ternary matrix was predominantly influenced by PCL and characterized by the development of a weak interface that failed due to matrix yielding. Furthermore, the incorporation of short fique fibers increased the elastic modulus of the composite to values similar to those estimated with the Tsai-Pagano model. The alkalization treatment of the fique fibers improved the interface with the composite matrix, and this phenomenon was evidenced by the results of the micromechanical and tensile characterizations of the composite.