Synthesis, microstructural, optical and mechanical properties of yttria stabilized zirconia thin films

Thin films of yttria-stabilized zirconia (YSZ) exhibit exceptional properties, such as high thermal, chemical and mechanical stability. Here, we report the synthesis of YSZ thin films by aerosol assisted chemical vapour deposition onto borosilicate glass and fused silica substrates. Optimum depositi...

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Detalles Bibliográficos
Autores: PATRICIA AMEZAGA MADRID, ABEL HURTADO MACIAS, WILBER ANTUNEZ FLORES, PEDRO PIZA RUIZ, MARIO MIKI YOSHIDA
Tipo de recurso: artículo
Estado:Versión enviada para evaluación y publicación
Fecha de publicación:2011
País:México
Institución:Centro de Investigación en Materiales Avanzados
Repositorio:Fuente de Objetos Científicos Open Access del CIMAV
Idioma:inglés
OAI Identifier:oai:cimav.repositorioinstitucional.mx:1004/1092
Acceso en línea:http://cimav.repositorioinstitucional.mx/jspui/handle/1004/1092
Access Level:acceso abierto
Palabra clave:info:eu-repo/classification/Vapour deposition/Thin film
info:eu-repo/classification/Optical properties/Microstructure
info:eu-repo/classification/SEM/Mechanical properties
info:eu-repo/classification/cti/1
info:eu-repo/classification/cti/22
info:eu-repo/classification/cti/2299
info:eu-repo/classification/cti/229999
Descripción
Sumario:Thin films of yttria-stabilized zirconia (YSZ) exhibit exceptional properties, such as high thermal, chemical and mechanical stability. Here, we report the synthesis of YSZ thin films by aerosol assisted chemical vapour deposition onto borosilicate glass and fused silica substrates. Optimum deposition temperatura was 673±5 K. In addition, different Y content was tried to analyse its influence in the microstructure and properties of the films. The films were uniform, transparent and non-light scattering. Surface morphology and cross sectional microstructure were studied by field emission scanning electron microscopy. The microstructure of the films was characterized by grazing incidence X-ray diffraction. Crystallite size and lattice parameter were obtained. Optical properties were analysed from reflectance and transmittance spectra; from these measurements, optical constants and band gap were obtained. Quantum confinement effect, due to the small grain size of the films, was evident in the high band gap energy obtained. Nanoindentation tests were realized at room temperature employing the continuous stiffness measurement method, to determine the hardness and elastic modulus as a function of Y content.