Self-Discharge of a Proton Exchange Membrane Electrolyzer: Investigation for Modeling Purposes

The self-discharge phenomenon results in a decrease of the open-circuit voltage (OCV), which occurs when an electrochemical device is disconnected from the power source. Although the self-discharge phenomenon has widely been investigated for energy storage devices such as batteries and supercapacito...

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Detalles Bibliográficos
Autores: Ángel Hernández-Gómez, VICTOR MANUEL RAMIREZ RIVERA, Damien Guilbert, Belem Saldivar
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:México
Institución:Centro de Investigación Científica de Yucatán
Repositorio:Repositorio Institucional CICY
Idioma:inglés
OAI Identifier:oai:cicy.repositorioinstitucional.mx:1003/2108
Acceso en línea:http://cicy.repositorioinstitucional.mx/jspui/handle/1003/2108
Access Level:acceso abierto
Palabra clave:info:eu-repo/classification/Autores/PEM ELECTROLYZER
info:eu-repo/classification/Autores/MODELING
info:eu-repo/classification/Autores/DYNAMIC MODEL
info:eu-repo/classification/Autores/SELF-DISCHARGE VOLTAGE
info:eu-repo/classification/cti/7
info:eu-repo/classification/cti/33
info:eu-repo/classification/cti/3322
info:eu-repo/classification/cti/531205
Descripción
Sumario:The self-discharge phenomenon results in a decrease of the open-circuit voltage (OCV), which occurs when an electrochemical device is disconnected from the power source. Although the self-discharge phenomenon has widely been investigated for energy storage devices such as batteries and supercapacitors, no previous works have been reported in the literature about this phenomenon for electrolyzers. For this reason, this work is mainly focused on investigating the self-discharge voltage that occurs in a proton exchange membrane (PEM) electrolyzer. To investigate this voltage drop for modeling purposes, experiments have been performed on a commercial PEM electrolyzer to analyze the decrease in the OCV. One model was developed based on different tests carried out on a commercial-400 W PEM electrolyzer for the self-discharge voltage. The proposed model has been compared with the experimental data to assess its effectiveness in modeling the self-discharge phenomenon. Thus, by taking into account this voltage drop in the modeling, simulations with a higher degree of reliability were obtained when predicting the behavior of PEM electrolyzers.