CO sensitivity of undoped-ZnO, Cr-ZnO and Cu-ZnO thin films obtained by spray pyrolysis

In this work, we present the gas–sensing properties of chemically sprayed undoped (ZnO), copper–doped (Cu–ZnO), and chromium–doped ZnO thin films (Cr–ZnO), in an atmosphere of carbon monoxide, CO. Films were deposited at 400°C, using zinc acetylacetonate as zinc precursor. Three different atomic con...

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Bibliographic Details
Authors: J.L. González–Vidal, M. de la L. Olvera, A. Maldonado, A. Reyes–Barranca, M. Meléndez–Lira
Format: article
Status:Published version
Publication Date:2006
Country:México
Institution:Universidad Autónoma del Estado de Hidalgo
Repository:Redalyc-UAEH
OAI Identifier:oai:redalyc.org:57028295002
Online Access:https://www.redalyc.org/articulo.oa?id=57028295002
Access Level:Open access
Keyword:Física, Astronomía y Matemáticas
Keywords
Zinc oxide
thin films
gas sensor
carbon monoxide
Description
Summary:In this work, we present the gas–sensing properties of chemically sprayed undoped (ZnO), copper–doped (Cu–ZnO), and chromium–doped ZnO thin films (Cr–ZnO), in an atmosphere of carbon monoxide, CO. Films were deposited at 400°C, using zinc acetylacetonate as zinc precursor. Three different atomic concentration ratios of the dopant were tested. A maximum sensitivity of the order of four orders of magnitude was obtained at measurement temperatures of 200 and 300°C in an atmosphere containing 100 ppm of CO. It was found that chromium doping favors a higher sensitivity at lower measurement temperatures (200°C), whereas the best sensitivity appears in copper–doped ZnO films at higher measurement temperatures (300° C). The thinnest films exhibited higher sensitivities.