Effect of cetyltrimethylammonium bromide on flocculation and filtration of bentonite suspensions

Separation of bentonite from wastewater is challenging because bentonite, is highly dispersible in water. Using cationic polymer flocculants has a high flocculation effect on bentonite. However, the flocculation mechanism is unclear. In this study, flocculation, filtration, and bentonite adsorption...

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Detalles Bibliográficos
Autores: Nakamura, A., Sato, H., Sato, Y., Murakami, K.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:México
Institución:UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO
Repositorio:Journal of Applied Research and Technology
Idioma:inglés
OAI Identifier:oai:ojs2.localhost:article/2112
Acceso en línea:https://jart.icat.unam.mx/index.php/jart/article/view/2112
Access Level:acceso abierto
Palabra clave:Cationic flocculant
adsorption
CTAB-bentonite
flocculation
filtration mechanism
Descripción
Sumario:Separation of bentonite from wastewater is challenging because bentonite, is highly dispersible in water. Using cationic polymer flocculants has a high flocculation effect on bentonite. However, the flocculation mechanism is unclear. In this study, flocculation, filtration, and bentonite adsorption behavior are investigated using cetyltrimethylammonium bromide (CTAB) as cationic small molecule; subsequently, the flocculation mechanism of bentonite is explored. The flocculation effect increases and the filtration time is reduced with increasing CTAB concentration. In particular, when more than 1500 ppm of CTAB is used, the filtration time is reduced to 2–3 min. Bentonite forms secondary flocculates after the formation of primary flocculates with increasing CTAB concentration. Additionally, the adsorption behavior reveals that CTAB is inserted between the layers, and it is excessively adsorbed on the bentonite surface. The increase CTAB concentration was effective in improving the shortening the filtration time owing to the formation of large bentonite flocculates.