Determination of the Thermal Diffusivity of Calcium Salts of Saturated Carboxylic Acids1

Calcium soaps are materials that serve a wide range of industrial applications such as softeners, detergents, plasticizers, greases, lubricants, cosmetics, and medicines. In addition, calcium salts of saturated carboxylic acids are of interest because of their presence in the staple food of Mexicans...

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Detalles Bibliográficos
Autores: STOLIK, S., VALOR, A., TOMAS, S.A., REGUERA, E.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2004
País:México
Institución:Instituto Politécnico Nacional
Repositorio:Repositorio Digital del IPN
OAI Identifier:oai:www.repositoriodigital.ipn.mx:123456789/11551
Acceso en línea:http://hdl.handle.net/123456789/1212
http://www.repositoriodigital.ipn.mx/handle/123456789/11551
Access Level:acceso abierto
Palabra clave:calcium salts
open photoacoustic cell
carboxylic acids
thermal diffusivity
Descripción
Sumario:Calcium soaps are materials that serve a wide range of industrial applications such as softeners, detergents, plasticizers, greases, lubricants, cosmetics, and medicines. In addition, calcium salts of saturated carboxylic acids are of interest because of their presence in the staple food of Mexicans and other Central American people: the corn tortilla. Because of their wide use in industry, a knowledge of the thermal properties of the alkaline metal soaps is of great importance. In the present work, the thermal diffusivity of butyric-Ca, valeric-Ca, caprilic-Ca, undecanoic-Ca, palmitic-Ca, and stearic-Ca salts has been determined by photoacoustics. The thermal diffusivity of these salts shows a linear dependence on the number of carbons in the aliphatic chain, and was found within the range 2.60×10−3 to 1.38×10−2 cm2 · s−1, with the highest and lowest values corresponding to butyric-Ca and stearic-Ca, respectively.