ADSORPTION AND SEPARATION OF LIGHT ALKANE HYDROCARBONS BY POROUS HEXACYANOCOBALTATES (III)

The adsorption and separation of light n-alkane hydrocarbons (propane, butane, pentane, hexane and heptane) by zinc and cadmium hexacyanocobaltates (III) were studied from inverse gas chromatographic data. These two solids are representative of the porous frameworks found for transition metals hexac...

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Detalles Bibliográficos
Autor: REGUERA RUIZ, EDILSO
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2009
País:México
Institución:Instituto Politécnico Nacional
Repositorio:Repositorio Digital del IPN
OAI Identifier:oai:www.repositoriodigital.ipn.mx:123456789/10567
Acceso en línea:http://hdl.handle.net/123456789/13
http://www.repositoriodigital.ipn.mx/handle/123456789/10567
Access Level:acceso abierto
Palabra clave:Porous solids
n-alkane separation
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spelling ADSORPTION AND SEPARATION OF LIGHT ALKANE HYDROCARBONS BY POROUS HEXACYANOCOBALTATES (III)REGUERA RUIZ, EDILSOPorous solidsn-alkane separationThe adsorption and separation of light n-alkane hydrocarbons (propane, butane, pentane, hexane and heptane) by zinc and cadmium hexacyanocobaltates (III) were studied from inverse gas chromatographic data. These two solids are representative of the porous frameworks found for transition metals hexacyanometallates. For cadmium, the porous framework is related to the presence of systematic vacancies for the building block, [Co(CN)6], while for Zn it is a consequence of a tetrahedral coordination for the Zn atom. These linear light hydrocarbons (paraffins) are effectively separated by these two porous frameworks. The involved differential adsorption heats and the related separation coefficients were estimated from the recorded chromatographic data. No significant differences for the separation ability of light n-alkane hydrocarbons by the evaluatedmaterials were observedEste artículo puede ser consultado en la revista Surface and interface AnalysisSurface And Interfase Analysis2012-03-06T23:43:14Z2012-03-06T23:43:14Z2009-04-282013-01-16T08:04:37Z2013-01-16T08:04:37Z2013-01-16info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/123456789/13http://www.repositoriodigital.ipn.mx/handle/123456789/10567reponame:Repositorio Digital del IPNinstname:Instituto Politécnico Nacionalinstacron:IPNesinfo:eu-repo/semantics/openAccessoai:www.repositoriodigital.ipn.mx:123456789/105672026-02-18T16:40:30Z
dc.title.none.fl_str_mv ADSORPTION AND SEPARATION OF LIGHT ALKANE HYDROCARBONS BY POROUS HEXACYANOCOBALTATES (III)
title ADSORPTION AND SEPARATION OF LIGHT ALKANE HYDROCARBONS BY POROUS HEXACYANOCOBALTATES (III)
spellingShingle ADSORPTION AND SEPARATION OF LIGHT ALKANE HYDROCARBONS BY POROUS HEXACYANOCOBALTATES (III)
REGUERA RUIZ, EDILSO
Porous solids
n-alkane separation
title_short ADSORPTION AND SEPARATION OF LIGHT ALKANE HYDROCARBONS BY POROUS HEXACYANOCOBALTATES (III)
title_full ADSORPTION AND SEPARATION OF LIGHT ALKANE HYDROCARBONS BY POROUS HEXACYANOCOBALTATES (III)
title_fullStr ADSORPTION AND SEPARATION OF LIGHT ALKANE HYDROCARBONS BY POROUS HEXACYANOCOBALTATES (III)
title_full_unstemmed ADSORPTION AND SEPARATION OF LIGHT ALKANE HYDROCARBONS BY POROUS HEXACYANOCOBALTATES (III)
title_sort ADSORPTION AND SEPARATION OF LIGHT ALKANE HYDROCARBONS BY POROUS HEXACYANOCOBALTATES (III)
dc.creator.none.fl_str_mv REGUERA RUIZ, EDILSO
author REGUERA RUIZ, EDILSO
author_facet REGUERA RUIZ, EDILSO
author_role author
dc.subject.none.fl_str_mv Porous solids
n-alkane separation
topic Porous solids
n-alkane separation
description The adsorption and separation of light n-alkane hydrocarbons (propane, butane, pentane, hexane and heptane) by zinc and cadmium hexacyanocobaltates (III) were studied from inverse gas chromatographic data. These two solids are representative of the porous frameworks found for transition metals hexacyanometallates. For cadmium, the porous framework is related to the presence of systematic vacancies for the building block, [Co(CN)6], while for Zn it is a consequence of a tetrahedral coordination for the Zn atom. These linear light hydrocarbons (paraffins) are effectively separated by these two porous frameworks. The involved differential adsorption heats and the related separation coefficients were estimated from the recorded chromatographic data. No significant differences for the separation ability of light n-alkane hydrocarbons by the evaluatedmaterials were observed
publishDate 2009
dc.date.none.fl_str_mv 2009-04-28
2012-03-06T23:43:14Z
2012-03-06T23:43:14Z
2013-01-16T08:04:37Z
2013-01-16T08:04:37Z
2013-01-16
dc.type.none.fl_str_mv info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/123456789/13
http://www.repositoriodigital.ipn.mx/handle/123456789/10567
url http://hdl.handle.net/123456789/13
http://www.repositoriodigital.ipn.mx/handle/123456789/10567
dc.language.none.fl_str_mv es
language_invalid_str_mv es
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Surface And Interfase Analysis
publisher.none.fl_str_mv Surface And Interfase Analysis
dc.source.none.fl_str_mv reponame:Repositorio Digital del IPN
instname:Instituto Politécnico Nacional
instacron:IPN
instname_str Instituto Politécnico Nacional
instacron_str IPN
institution IPN
reponame_str Repositorio Digital del IPN
collection Repositorio Digital del IPN
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.811543

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