Ethane Internal Rotation -Vibrational Hamiltonian

One of the main purposes of a theoretical spectroscopist is topropose a model to reproduce the xperimental spectra available in theliterature as accurate and with as much physical information as possible.In this case it has been studied the Far infrared an Infrared spectraof non-rigid molecules, int...

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Detalles Bibliográficos
Autores: David Ricardo Hidalgo Olguín, María Villa, María Luisa Senent, Marco Antonio Mora Delgado
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2008
País:México
Institución:Universidad Autónoma Metropolitana
Repositorio:Redalyc-UAM
OAI Identifier:oai:redalyc.org:47552115
Acceso en línea:https://www.redalyc.org/articulo.oa?id=47552115
Access Level:acceso abierto
Palabra clave:Química
FIR
Ethane
ab initio
IR Spectrum
Descripción
Sumario:One of the main purposes of a theoretical spectroscopist is topropose a model to reproduce the xperimental spectra available in theliterature as accurate and with as much physical information as possible.In this case it has been studied the Far infrared an Infrared spectraof non-rigid molecules, introducing in the Vibrational Potential theirdependence on the large amplitude variables. The molecule that hasbeen selected to test our proposed Hamiltonian is ethane which is avery well studied molecule. The molecule is a non-rigid molecule andtheir experimental spectra have been reported in the literature.